2-methyl-3,3-diphenyl-acrylic acid ethyl ester | 65127-37-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-methyl-3,3-diphenyl-acrylic acid ethyl ester
• 英文别名: 2-Methyl-3,3-diphenyl-acrylsaeure-aethylester；Ethyl 2-methyl-3,3-diphenylprop-2-enoate
• CAS: 65127-37-9
• 化学式: C₁₈H₁₈O₂
• 分子量: 266.34
• InChiKey: BVMLNZOYMMKCFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-methyl-3,3-diphenyl-acrylic acid ethyl ester 在 氢氧化钾 作用下， 生成 2-甲基-3,3-二苯基丙-2-烯酸
  参考文献：
  名称：

  de Fazi, Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1916, vol. <5> 25 I, p. 97

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 盐酸 作用下， 生成 2-methyl-3,3-diphenyl-acrylic acid ethyl ester
  参考文献：
  名称：

  Gliotoxin. V. The Structure of Certain Indole Derivatives Related to Gliotoxin^1,2

  摘要：

  DOI：

  10.1021/ja01219a023

文献信息

• Ethics and Foreign Policy: The Antinomies of New Labour's ‘Third Way’ in Sub-Saharan Africa
  作者：Rita Abrahamsen、Paul Williams

  DOI：10.1111/1467-9248.00312

  日期：2001.6

  This article explores how New Labour has attempted to implement its ideas about a ‘third way’ foreign policy in sub-Saharan Africa. Through an examination of British foreign policy practices, we explore whether New Labour has succeeded in finding a ‘third way’ between traditional views of socialism and capitalism in Africa. In particular, the article focuses on New Labour's attempts to build peace, prosperity and democracy on the African continent. We conclude that although New Labour's claims to add an ‘ethical dimension’ to foreign policy have succeeded in giving Britain a higher profile in the international arena, the implementation of such a policy is intrinsically difficult. These difficulties in turn arise from the antinomies embodied in New Labour's policy, or more specifically from the tension between the liberal internationalism of the third way and traditional concerns for the national interest, as well as the contradictions inherent in a commitment to both political and economic liberalism.

  这篇文章探讨了新工党如何试图在撒哈拉以南非洲实施其关于“第三条道路”外交政策的想法。通过对英国外交政策实践的审查，我们探讨新工党是否成功地在非洲传统社会主义和资本主义观念之间找到了一种“第三条道路”。特别是，文章关注新工党在非洲大陆上建立和平、繁荣和民主的努力。我们得出结论，尽管新工党声称在外交政策中增加了“道德维度”成功地使英国在国际舞台上更加引人注目，但这种政策的实施本质上是困难的。这些困难反过来源于新工党政策所体现的矛盾，更具体地说，源于第三条道路的自由国际主义与对国家利益的传统关注之间的紧张关系，以及对政治和经济自由主义的承诺中固有的矛盾。
• AN INTERPRETATION OF THE SUBSTITUENT EFFECT IN THE BLAISE REARRANGEMENT IN TERMS OF PI-ORBITALS
  作者：Yukio Abe、Tadashi Suehiro

  DOI：10.1246/cl.1983.389

  日期：1983.3.5

  The migratory aptitude of the substituent groups in the Blaise rearrangement can be explained in terms of the pi-electronic properties of the groups in the highest occupied molecular orbitals. The rates of the rearrangement reaction with relation to the substituent groups were also rationally understood based on the energy levels of the molecular orbitals.

  Blaise 重排中取代基的迁移能力可以用最高占据分子轨道中基团的 pi 电子特性来解释。基于分子轨道的能级，也可以合理地理解与取代基相关的重排反应速率。
• Vinyl anions. Part 9. Vinyl carbanions derived from acrylic esters and their β-phenyl derivatives
  作者：Ben Ami Feit、Uri Melamed、Richard R. Schmidt、Heike Speer

  DOI：10.1039/p19810001329

  日期：——

  carbanions. The vinyl carbanions were treated with various electrophiles to give the corresponding α-substituted derivatives. Ethyl cis- and trans-cinnamate gave mostly β-substituted products having trans-geometry. The products obtained from the maleic esters were the corresponding fumarate derivatives. Deuteriation of ethyl cis-cinnamate gave the α-deuteriated ethyl cis-cinnamate. In the absence of an added

  将ββ-二苯基丙烯酸乙酯，顺式和反式肉桂酸乙酯，马来酸甲酯和乙酯，富马酸乙酯和丙烯酸甲酯在低温下用强碱处理，得到衍生的乙烯基碳负离子。用各种亲电子试剂处理乙烯基碳负离子，得到相应的α-取代的衍生物。顺式和反式肉桂酸乙酯大部分给出具有反式几何结构的β-取代产物。从马来酸酯得到的产物是相应的富马酸酯衍生物。顺式肉桂酸乙酯的氘化反应得到α-氘化的顺式乙酯-肉桂 在不添加亲电试剂的情况下，分离出顺式和反式肉桂酸乙酯的二聚体和三聚体。还研究了溶剂，碱和温度的影响。
• COMPOSITION FOR DISPLAY SEALING MATERIAL, ORGANIC PROTECTION LAYER COMPRISING SAME, AND DISPLAY DEVICE COMPRISING SAME
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20170298164A1

  公开（公告）日：2017-10-19

  The present invention relates to a composition for a display sealing material having a photopolymerization initiator and a photocurable monomer, the photocurable monomer comprising: a monomer not having the aromatic hydrocarbon group; and a monomer having two or more substituted or unsubstituted phenyl groups of chemical formula 1, wherein about 5 wt % to about 45 wt % of the monomer having two or more substituted or unsubstituted phenyl groups is comprised on the basis of the photocurable monomer and about 55 wt % to about 95 wt % of the monomer not having the aromatic hydrocarbon group is comprised on the basis of the photocurable monomer.

  本发明涉及一种用于显示密封材料的组合物，其具有光聚合引发剂和光固化单体，所述光固化单体包括：不具有芳香族碳氢基团的单体；以及具有两个或更多取代或未取代苯基的化学式1的单体，其中以具有两个或更多取代或未取代苯基的单体为基础，包含约5重量％至约45重量％，以不具有芳香族碳氢基团的单体为基础，包含约55重量％至约95重量％。
• Composition for display sealing material, organic protection layer comprising same, and display device comprising same
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US10316112B2

  公开（公告）日：2019-06-11

  A display sealing material composition includes a photopolymerization initiator and a photocuring monomer, the photocuring monomer comprising: a monomer not having the aromatic hydrocarbon group; and a monomer having two or more substituted or unsubstituted phenyl groups. An organic protection layer obtained by curing the composition for a display sealing material has approximately 400 nm/min or less plasma etching rate being represented by formula 1 below and approximately 2 nm or less surface roughness. Plasma etching rate(nm/min)=(T0−T1)/M,   wherein T0, T1, and M are set forth in the specification.

  一种显示密封材料组合物包括光聚合引发剂和光固化单体，光固化单体包括：不具有芳香烃基团的单体；具有两个或两个以上取代或未取代苯基的单体。通过固化用于显示器密封材料的组合物而获得的有机保护层，等离子刻蚀速率约为 400 nm/min 或更低，如下式 1 所示，表面粗糙度约为 2 nm 或更低。 等离子刻蚀速率（纳米/分钟）=（T0-T1）/M、 其中 T0、T1 和 M 见说明书。