| 533901-62-1

• CAS: 533901-62-1
• 化学式: C₂₉H₃₀Cl₄SiTiZr
• 分子量: 687.559
• InChiKey: GZECDBXOZYLDIW-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (benzyl)cyclopentadienyltitanium trichloride 、 以 甲苯 为溶剂， 以38.2%的产率得到
  参考文献：
  名称：

  Synthesis of hetero-bimetallic metallocene complexes and their catalytic activities for ethylene polymerization

  摘要：

  Five new hetero-bimetallic metallocene complexes were synthesized by the reaction of RCpTiCl3 and a Si-bridged zirconocene complex in refluxing toluene. They were all well characterized. These complexes activated with methylaluminoxane (MAO) are highly active catalysts for the polymerization of ethylene. The molecular weight (M-w = 28,957-124,089) and the molecular weight distribution (MWD = 2.04-3.01) of the polymer generated from the bimetallic catalytic system were higher than that obtained by CP2ZrCl2. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(02)00361-8