bis(3-aminophenoxy)biphenyl | 152585-01-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(3-aminophenoxy)biphenyl
• 英文别名: 3-[2-[2-(3-Aminophenoxy)phenyl]phenoxy]aniline
• CAS: 152585-01-8
• 化学式: C₂₄H₂₀N₂O₂
• 分子量: 368.435
• InChiKey: XHLZBSBXIJSBRV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  28
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  70.5
• 氢给体数：
  2
• 氢受体数：
  4

文献信息

• [EN] METHOD OF PURIFYING DIANHYDRIDES, THE DIANHYDRIDES FORMED THEREBY, AND POLYETHERIMIDES FORMED THEREFROM<br/>[FR] PROCÉDÉ DE PURIFICATION DES DIANHYDRIDES, DIANHYDRIDES AINSI OBTENUS, ET POLYÉTHERIMIDES FORMÉS À PARTIR DE CEUX-CI
  申请人：SABIC INNOVATIVE PLASTICS IP

  公开号：WO2009120212A1

  公开（公告）日：2009-10-01

  A method for purifying an oxydiphthalic anhydride comprises diluting a first mixture comprising an oxydiphthalic anhydride, a solvent, a catalyst, and an inorganic salt with a solvent, to provide a second mixture having a solids content of 10 to 30 percent based on total weight of the second mixture; filtering and washing the solids of the second mixture at a temperature below the crystallization point temperature of the oxydiphthalic anhydride to provide a third mixture; hydrolyzing the third mixture by adding water and a water-soluble acid to form a fourth mixture; heating the fourth mixture; then cooling to provide a solid-liquid mixture, optionally decanting a portion of the liquid, re diluting the remaining solid-liquid mixture, then filtering to provide a solid component; washing the solid component with water to provide a fifth mixture of oxydiphthalic tetra acid and water; ring closing the oxydiphthalic tetra acid to provide oxydiphthalic anhydride, and filtering the oxydiphthalic anhydride.

  一种用于纯化氧二苯二甲酸酐的方法包括将含有氧二苯二甲酸酐、溶剂、催化剂和无机盐的第一混合物稀释至含固体物含量为总重量的10至30％的第二混合物；在低于氧二苯二甲酸酐的结晶点温度的温度下过滤和洗涤第二混合物的固体以提供第三混合物；通过加入水和水溶性酸水解第三混合物以形成第四混合物；加热第四混合物；然后冷却以提供固液混合物，可选择性地倾倒部分液体，重新稀释剩余的固液混合物，然后过滤以提供固体组分；用水洗涤固体组分以提供氧二苯四甲酸和水的第五混合物；闭环氧二苯四甲酸以提供氧二苯二甲酸酐，并过滤氧二苯二甲酸酐。
• Preparation process of isoimide
  申请人：Mitsui Chemicals, Inc.

  公开号：EP0846714A1

  公开（公告）日：1998-06-10

  A preparation process of isoimide comprising reacting a compound having one or more carboxyl group and one or more amide bond in the same molecule in the presence of a haloiminium salt and basic substance, and a preparation process of isoimide comprising reacting a compound having one or more carboxyl group with a compound having one or more amide bond in the presence of a haloiminium salt and basic substance are disclosed.

  本发明公开了一种制备异咪酰亚胺的过程，包括在卤代铵盐和碱性物质的存在下，反应具有一个或多个羧基和一个或多个酰胺键的化合物，以及在卤代铵盐和碱性物质的存在下，反应具有一个或多个羧基的化合物和具有一个或多个酰胺键的化合物的制备过程。
• AROMATIC BISMALEIMIDO COMPOUNDS AND PROCESS FOR THEIR PREPARATION
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0253891A1

  公开（公告）日：1988-01-27

  Novel aromatic bismaleimido compounds represented by general formula (I): (wherein X represents (III), (lVI, (V) or (VI) (wherein R1, R2, R3 and R4 each represents a hydrogen atom or a methyl group)). These compounds are prepared by reacting a diamine represented by general formula (II) (wherein X is the same as defined above) with maleic anhydride and cyclizing the formed aromatic bismaleamic acid

  由通式(I)代表的新型芳香族双马来酰亚胺化合物：(其中 X 代表(III)、(lVI)、(V)或(VI)（其中 R1、R2、R3 和 R4 各自代表氢原子或甲基））。这些化合物的制备方法是将通式(II)代表的二胺（其中 X 与上述定义相同）与马来酸酐反应，并使形成的芳香族双马来酰胺酸环化
• Thermosetting resin composition
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0288251A1

  公开（公告）日：1988-10-26

  A thermosetting resin composition formed of a polyaminobismaleimide resin, which is composed of a bismaleimide compound I and a diamine compound II, and a fibrous reinforcing material. The composition has excellent impact resistance and toughness while retaining conventional high heat resistance.

  一种由聚氨基双马来酰亚胺树脂（由双马来酰亚胺化合物 I 和二胺化合物 II 组成）和纤维增强材料形成的热固性树脂组合物。该组合物具有优异的抗冲击性和韧性，同时保留了传统的高耐热性。
• Polyimide resin composition
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0294195A2

  公开（公告）日：1988-12-07

  Resin composition composed of 99.9 to 50 % by weight of a polyimide having a repeating unit of the formula as defined below and 0.1 to 50 % by weight of an aromatic polyamideimide are improved in heat resistance and mechanical strength and have the inherent properties of polyimide; where X indicates a direct bond or is -S- or and R is a tetravalent radical selected from the group consisting of aliphatic radicals having at least 2 carbon atoms, cycloaliphatic radicals, monocycloaromatic radicals and condensed polycycloaromatic radicals, and uncon­densed polycycloaromatic radicals including aromatic radicals interconnected directly or through a cross-linkage.

  由 99.9%至 50%（按重量计）具有下式定义的重复单元的聚酰亚胺和 0.1%至 50%（按重量计）芳香族聚酰胺酰亚胺组成的树脂组合物，其耐热性和机械强度得到改善，并具有聚酰亚胺的固有特性； 其中 X 表示直接键或 -S- 或 和 R 是四价基，选自由至少有 2 个碳原子的脂肪族基、环脂族基、单环芳香族基和 缩合多环芳香族基和未缩合多环芳香族基（包括直接或通过交联相互连接的芳香族基）所 组成的组。