Divinylphosphinsaeure-phenylester | 30594-16-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Divinylphosphinsaeure-phenylester
• 英文别名: Bis(ethenyl)phosphoryloxybenzene
• CAS: 30594-16-2
• 化学式: C₁₀H₁₁O₂P
• 分子量: 194.17
• InChiKey: LWRFRRHRVUVZGI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  Bis-<2-chlor-aethyl>-phosphinsaeure-phenylester 生成 Divinylphosphinsaeure-phenylester
  参考文献：
  名称：

  有机磷素44化合物和特征化合物-（ß-氯基）-膦酸酯-衍生物[1] †

  摘要：

  ClCH 2 CH 2 PCl 2与环氧乙烷反应生成亚膦酸酯ClCH 2 CH 2 P（OCH 2 CH 2 Cl）2，加热至120°时会重排成次膦酸酯（ClCH 2 CH 2）2 P（ O）OCH 2 CH 2 Cl（3）。在CCl 4溶液中用PCl 5氯化3产生次膦酰氯（ClCH 2 CH 2）P（O）Cl（4），将其用P处理在170°下的2 S 5生成硫代衍生物（ClCH 2 CH 2）2 P（S）Cl，（5）。在酸结合剂的存在下用醇，硫醇或胺处理4和5可得到相应的次膦酸和硫代次膦酸衍生物（ClCH 2 CH 2）P（X）Y，（X = O，S; Y = OR，SR，NR 2）（6）。的反应6与过量碱，得到相应的divinylphosphinic和divinylthiophosphinic酸衍生物（CH 2 = CH）2 P（X）Y（X = O，S; Y = OR，SR，NR 2）（7）。

  DOI：

  10.1002/hlca.19710540124

文献信息

• Levin,Ya.A.; Pyrkin,R.I., Journal of general chemistry of the USSR, 1973, vol. 43, p. 580 - 582
  作者：Levin,Ya.A.、Pyrkin,R.I.

  DOI：——

  日期：——
• FLAME-RETARDANT RESIN PROCESSED ARTICLE
  申请人：Kanno Toshiyuki

  公开号：US20090048377A1

  公开（公告）日：2009-02-19

  Disclosed is a flame-retardant resin processed article having excellent flame retardance while being free from bleed-out. Specifically, a resin composition containing a cyclic phosphorus compound flame retardant, a hydrophilic silica powder having an average particle diameter of not more than 15 m, and a resin with the total content of the cyclic phosphorus compound and the hydrophilic silica powder being 10-45% by mass is molded into a certain shape or formed into a coating film. The hydrophilic silica powder is preferably composed of porous structures having a pore volume of not more than 1.8 ml/g and a pH of 4-7. More preferably, the hydrophilic silica powder has an oil absorption of not less than 50 ml/100 g in accordance with JIS K5101.
• FLAME RETARDANT RESIN TREATED ARTICLE
  申请人：Kanno Toshiyuki

  公开号：US20090105382A1

  公开（公告）日：2009-04-23

  A flame retardant resin treated article that excels in flame retardancy and is free from bleedout. A resin composition comprising a flame retarder of metal phosphinate represented by the general formula: (I) (in the formula, each of R 1 and R 2 is a C 1 -C 6 alkyl or an aryl group having 12 or less carbon atoms; M is calcium, aluminum or zinc; and when M=aluminum, m=3, and otherwise m=2), a reactive organophosphorus flame retarder having an unsaturated group at its terminal and a resin wherein the total content of metal phosphinate and reactive organophosphorus flame retarder is in the range of 5 to 30 mass % is provided in molded form or coating form.
• FLAME-RESISTANT RESIN COMPOSITION
  申请人：SUGATA Yoshinobu

  公开号：US20100113654A1

  公开（公告）日：2010-05-06

  A flame-resistant resin composition is disclosed that uses a non-halogen flame retardant as the flame retardant, and allows resin processed articles to be obtained which have superior flame resistance and heat resistance. The flame-resistant resin composition comprises a non-halogen flame retardant (A) containing a metal phosphinate (a) represented by the following formula (I) wherein, R1 and R2 respectively represent an alkyl group having 1 to 6 carbon atoms or an aryl group having 12 carbon atoms or less, M represents calcium, aluminum or zinc, m=3 when M is aluminum, and m=2 when M is other than aluminum, and an organic phosphorous flame retardant (b), an isocyanurate compound (B) having one or more glycidyl groups in the molecular structure thereof, and a thermoplastic resin (C).
• US7834071B2
  申请人：——

  公开号：US7834071B2

  公开（公告）日：2010-11-16