[(Pt(CH2C6H4P(o-tolyl)2-κC,P)(μ-3,5-dimethylpyrazole))2] | 475578-44-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 咪唑并吡啶类
• 英文名称: [(Pt(CH2C6H4P(o-tolyl)2-κC,P)(μ-3,5-dimethylpyrazole))2]
• CAS: 475578-44-0
• 化学式: C₅₂H₅₄N₄P₂Pt₂
• 分子量: 1187.14
• InChiKey: ZEGCEMBUMWYHJS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(Pt(CH2C6H4P(o-tolyl)2-κC,P)(μ-3,5-dimethylpyrazole))2] 、 silver perchlorate 以 乙醚 、 二氯甲烷 为溶剂， 以79%的产率得到[(Pt(CH2C6H4P(o-tolyl)2-κC,P)(μ-3,5-dimethylpyrazole))2Ag]ClO4
  参考文献：
  名称：

  Synthesis and Reactivity of the Neutral Pyrazolate Complexes [M₂{CH₂C₆H₄P(o-tolyl)₂-κC,P}₂(μ-Rpz)₂] (M = Pd, Pt; Rpz = Pz, 3,5-dmpz, 4-Mepz) toward AgClO₄. Molecular Structure of [Pt₂Ag{CH₂C₆H₄P(o-tolyl)₂-κC,P}₂(μ-4-Mepz)₂]ClO₄

  摘要：

  The neutral compounds [Pt-2{CH2C6H4P(o-tolyl)(2)-kappaC,P}(2)(mu-Rpz)(2)] (Rpz = pz (2a), 3,5-dmpz (2b), 4-Mepz (2c)) react with AgClO4 in a 1:1 molar ratio to give the trinuclear compounds [Pt2Ag{CH2C6H4P(o-tolyl)(2)-kappaC,P}(2)(mu-Rpz)(2)]ClO4 (Rpz = pz (4a), 3,5-dmpz (4b), 4-Mepz (4c)), which contain two Pt-Ag bonds. The reaction of [Pd-2{CH2C6H4P(o-tolyl)(2)-kappaC,P}(2)(mu-3,5-dmpz)(2)] (3b) with AgClO4 renders [{Pd-2(CH2C6H4P(o-tolyl)(2)-kappaC,P)(2)(mu(3)-3,5-dmpz-N,N',C-4)(2)Ag(eta(2)-mu(2)-ClO4)}(2)] (5), a palladium/silver compound with an unprecedented dmpz bridging ligand eta(1)-bonded to the Ag centers, a coordination mode involving only the C-4 atom of each dmpz ligand.

  DOI：

  10.1021/om0203835
• 作为产物：
  描述：

  3,5-二甲基吡唑 、 [(Pt(CH2C6H4P(o-tolyl)2-κC,P)(μ-acetato))2] 在 triethyl amine 作用下， 以 甲醇 为溶剂， 以80.5%的产率得到[(Pt(CH2C6H4P(o-tolyl)2-κC,P)(μ-3,5-dimethylpyrazole))2]
  参考文献：
  名称：

  Synthesis and Reactivity of the Neutral Pyrazolate Complexes [M₂{CH₂C₆H₄P(o-tolyl)₂-κC,P}₂(μ-Rpz)₂] (M = Pd, Pt; Rpz = Pz, 3,5-dmpz, 4-Mepz) toward AgClO₄. Molecular Structure of [Pt₂Ag{CH₂C₆H₄P(o-tolyl)₂-κC,P}₂(μ-4-Mepz)₂]ClO₄

  摘要：

  The neutral compounds [Pt-2{CH2C6H4P(o-tolyl)(2)-kappaC,P}(2)(mu-Rpz)(2)] (Rpz = pz (2a), 3,5-dmpz (2b), 4-Mepz (2c)) react with AgClO4 in a 1:1 molar ratio to give the trinuclear compounds [Pt2Ag{CH2C6H4P(o-tolyl)(2)-kappaC,P}(2)(mu-Rpz)(2)]ClO4 (Rpz = pz (4a), 3,5-dmpz (4b), 4-Mepz (4c)), which contain two Pt-Ag bonds. The reaction of [Pd-2{CH2C6H4P(o-tolyl)(2)-kappaC,P}(2)(mu-3,5-dmpz)(2)] (3b) with AgClO4 renders [{Pd-2(CH2C6H4P(o-tolyl)(2)-kappaC,P)(2)(mu(3)-3,5-dmpz-N,N',C-4)(2)Ag(eta(2)-mu(2)-ClO4)}(2)] (5), a palladium/silver compound with an unprecedented dmpz bridging ligand eta(1)-bonded to the Ag centers, a coordination mode involving only the C-4 atom of each dmpz ligand.

  DOI：

  10.1021/om0203835