1-(2,4,6-三氯苯基)-3-(5-十四酰胺基-2-氯苯胺基)-5-吡唑酮 | 54636-84-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-(2,4,6-三氯苯基)-3-(5-十四酰胺基-2-氯苯胺基)-5-吡唑酮
• 中文别名: N-[4-氯-3-[[4,5-二氢-5-氧代-1-(2,4,6-三氯苯基)-1H-吡唑-3-基]氨基]苯基]十四烷酰胺；1-(2,4,6-三氯苯基)-3-[2'-氯-5'-(十四碳酰氨基)苯氨基]-5-吡唑啉酮
• 英文名称: 5-(2-chloro-5-tetradecanoylamino-anilino)-2-(2,4,6-trichloro-phenyl)-1,2-dihydro-pyrazol-3-one
• 英文别名: N-(4-chloro-3-{[4,5-dihydro-5-oxo-1-(2,4,6-trichlorophenyl)-1H-pyrazol-3-yl]amino}phenyl)myristamide；Tetradecanamide, n-[4-chloro-3-[[4,5-dihydro-5-oxo-1-(2,4,6-trichlorophenyl)-1h-pyrazol-3-yl]amino]phenyl]-；N-[4-chloro-3-[[5-oxo-1-(2,4,6-trichlorophenyl)pyrazolidin-3-ylidene]amino]phenyl]tetradecanamide
• CAS: 54636-84-9
• 化学式: C₂₉H₃₆Cl₄N₄O₂
• 分子量: 614.442
• InChiKey: UDVIVSCMZQLZQL-UHFFFAOYSA-N

物化性质

• 物理描述：
  DryPowder

计算性质

• 辛醇/水分配系数(LogP)：
  10.3
• 重原子数：
  39
• 可旋转键数：
  16
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  73.8
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-(2,4,6-三氯苯基)-3-(5-十四酰胺基-2-氯苯胺基)-5-吡唑酮 在 selenium(IV) oxide 作用下， 以 1,4-二氧六环 为溶剂， 反应 6.0h， 生成 N-[4-chloro-3-[[4-[[3-[2-chloro-5-(tetradecanoylamino)anilino]-5-oxo-1-(2,4,6-trichlorophenyl)-4H-pyrazol-4-yl]seleninyl]-5-oxo-1-(2,4,6-trichlorophenyl)-4H-pyrazol-3-yl]amino]phenyl]tetradecanamide
  参考文献：
  名称：

  Bergthaller, Peter, Angewandte Chemie, 1991, vol. 103, # 12, p. 1742 - 1743

  摘要：

  DOI：

文献信息

• Silver halide color light sensitive material
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04734357A1

  公开（公告）日：1988-03-29

  A silver halide color light-sensitive material is described, which is increased in sensitivity, is adapted to form an image of high contrast, or is accelerated in development by incorporating a small amount of a specific compound which imagewise releases a foggant or a development accelerator. This compound is represented by the formula: Coup-(TIME).sub.n -FA (wherein Coup represents a coupler radical capable of undergoing a coupling reaction with an oxidized product of an aromatic primary amine developing agent; TIME represents a timing group which is eliminated from Coup by the coupling reaction and, thereafter, releases FA; n is 0 or 1; and FA represents a group which is eliminated from Coup in the coupling reaction when n is 0, whereas FA is released from TIME when n is 1. The FA has adsorption properties with respect to silver halide grains and also has a substantial fogging action with respect to the silver halide grains).

  本文描述了一种银卤化物彩色感光材料，通过加入少量的特定化合物，可以增加其灵敏度、适用于高对比度的图像形成，或者加速显影过程。该化合物的化学式为：Coup-(TIME).sub.n -FA，其中Coup代表一个偶联试剂基团，能够与芳香族一级胺显影剂的氧化产物发生偶联反应；TIME代表一个计时基团，通过偶联反应从Coup中消除，并随后释放FA；n为0或1；FA代表在n为0时从Coup中消除的基团，而在n为1时从TIME中释放的基团。FA对银卤化物颗粒具有吸附特性，并且对银卤化物颗粒具有显著的起雾作用。
• Silver halide color photographic materials
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04264723A1

  公开（公告）日：1981-04-28

  Silver halide color photographic sensitive materials which comprise photographic layers containing at least one of the couplers represented by the following general formula (I): ##STR1## wherein R.sub.1 represents an anilino group, an acylamino group or a ureido group, R.sub.2 represents an alkyl group, an aralkyl group or an alkenyl group, X.sub.1, X.sub.2 and X.sub.3 each represents a hydrogen atom, an alkyl group, a halogen atom, an alkoxy group, an aryloxy group, an acylamino group, a carbamoyl group, a sulfamoyl group, a sulfonyl group, a cyano group or an alkoxycarbonyl group and X.sub.1, X.sub.2 and X.sub.3 may be the same or different, are disclosed.

  本发明涉及一种银卤化物彩色感光材料，其包含至少一种以下通式（I）所代表的偶联剂的感光层： 其中R1代表苯胺基、酰胺基或脲基，R2代表烷基、芳基烷基或烯基，X1、X2和X3分别代表氢原子、烷基、卤素原子、烷氧基、芳氧基、酰胺基、氨基甲酰基、磺酰基、氰基或烷氧羰基，且X1、X2和X3可以相同也可以不同。
• Photographic material containing 2-acyl-2-pyrazolin-5-on-couplers
  申请人：AGFA-Gevaert, N.V.

  公开号：US04061498A1

  公开（公告）日：1977-12-06

  2-Acyl-3-pyrazolin-5-one couplers are provided for use in color photography which upon color development form 2-pyrazolin-5-one couplers capable of coupling with the oxidation products of the color developing agent.

  提供了2-酰基-3-吡唑啉-5-酮偶联剂，用于彩色摄影，其在彩色显影后形成能够与彩色显影剂氧化产物偶联的2-吡唑啉-5-酮偶联剂。
• Photographic silver halide color material containing fast-acting
  申请人：Agfa-Gevaert N.V.

  公开号：US04123281A1

  公开（公告）日：1978-10-31

  Color photographic material containing a fast-acting hardener, which acts by activating carboxyl groups, wherein said material contains a 2-pyrazolin-5-one coupler precursor corresponding to one of the following general formulae I or II: ##STR1## wherein EACH OF R.sup.1, R and Y are substituents of the type used in 2-pyrazolin-5-one color couplers, and Z represents acyl, alkoxycarbonyl, aryloxycarbonyl, Or ##STR2## in which R.sup.1, R, and Y have the above-defined significance, and A represents an alkylene group or an arylene group.

  含有快速作用硬化剂的彩色照相材料，其通过激活羧基基团起作用，其中所述材料含有与下列通式I或II之一相对应的2-吡唑烷-5-酮偶合剂前体：##STR1## 其中R1、R和Y分别是2-吡唑烷-5-酮色偶联剂中使用的类型的取代基，Z代表酰基、烷氧基羰基、芳基氧基羰基或##STR2## 其中R1、R和Y具有上述定义的意义，A代表烷基或芳基。
• Silver halide color photographic light-sensitive material
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04628024A1

  公开（公告）日：1986-12-09

  A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer and a compound represented by the following general formula (I): ##STR1## wherein COUP represents a coupler residue capable of being subjected to a coupling reaction with an oxidation product of an aromatic primary amine developing agent; TIME represents a timing group which is released upon the coupling reaction and subsequently releases ##STR2## Z represents a monocyclic or condensed heterocyclic ring consisting of a nitrogen atom and a carbon atom; L represents a divalent linking group; R.sup.1 represents a hydrogen atom or an alkoxycarbonyl group; R.sup.2 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a thioacyl group or a thiocarbamoyl group; R.sup.3 represents a hydrogen atom; R.sup.2 and R.sup.3 may be bonded each other to form a hydrazone structure; a part of L and R.sup.1 may be bonded each other to form a hydrazone structure; and n represents 0 or 1. The silver halide color photographic light-sensitive material containing the compound capable of imagewise releasing a fogging agent represented by the general formula (I) is improved in stability during preservation and has a high contrast and sensitivity. A method of forming a color image using the silver halide color photographic light-sensitive material is also disclosed.

  一种银卤化物彩色摄影感光材料，包括支撑物上的银卤化物乳液层和下列一般式（I）所代表的化合物：##STR1##其中COUP代表能够与芳香族原始胺显影剂的氧化产物进行偶联反应的偶联剩基；TIME代表在偶联反应中释放并随后释放##STR2##的定时组；Z代表由一个氮原子和一个碳原子组成的单环或缩合杂环；L代表二价连结基；R.sUP.1代表氢原子或烷氧羰基基团；R.sUP.2代表氢原子、烷基、芳基、杂环基、酰基、磺酰基、烷氧羰基基团、氨基甲酰基基团、磺酰胺基基团、硫代酰基或硫代氨基甲酰基基团；R.sUP.3代表氢原子；R.sUP.2和R.sUP.3可以结合形成肼酮结构；L和R.sUP.1的一部分可以结合形成肼酮结构；n代表0或1。含有能够像图像地释放由一般式（I）所代表的雾化剂的化合物的银卤化物彩色摄影感光材料在保存期间具有较高的稳定性、对比度和灵敏度。还公开了使用该银卤化物彩色摄影感光材料形成彩色图像的方法。