[Ni(2,4'-bpy)2(CCl2HCOO)2]*2H2O | 784202-40-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Ni(2,4'-bpy)2(CCl2HCOO)2]*2H2O
• 英文别名: [Ni(2,4'-bipyridine)2(dichloroacetate)2]*2H2O
• CAS: 784202-40-0
• 化学式: C₂₄H₂₂Cl₄N₄NiO₆
• 分子量: 662.964
• InChiKey: NEXQRMVILQXZIL-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  [Ni(2,4'-bpy)2(CCl2HCOO)2]*2H2O 以 neat (no solvent) 为溶剂， 生成 nickel(II) oxide
  参考文献：
  名称：

  Synthesis, thermal and other studies of 2,4'-bipyridine-dichloroacetato complexes of Mn(II), Co(II), Ni(II) and Cu(II)

  摘要：

  Four new mixed ligand complexes were prepared by the reaction of title metal dichloroacetates and 2,4'-bipyridine. The general formulae of synthesized compounds are M(2,4'-bPY)(2)(CCl2HCOO)(2).nH(2)O (where M(II)=Mn, Co, Ni, Cu; 2,4'-bpy=2,4'-bipyridine, n=2 or 4). The complexes have been isolated from aqueous media and characterized by chemical analysis, molar conductance (in MeOH, DMSO and DMF), magnetic, IR and VIS spectral studies. The nature of metal(II)-ligand coordination is discussed. The thermal behaviour of obtained complexes was studied by thermal analysis and TG-MS techniques in air. IR, X-ray powder diffraction and thermoanalytical data were used for the determination of solid intermediate products of the thermal decomposition. The principal volatile products of thermal decomposition of complexes were proved by mass spectroscopy: H2O+, CO2+, HCI+, Cl-2(+), NO+ and other.

  DOI：

  10.1023/b:jtan.0000028033.91256.c6