bis-(4-amino-2-trifluoromethyl-phenyl)-sulfone | 384-36-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis-(4-amino-2-trifluoromethyl-phenyl)-sulfone
• 英文别名: 3,3'-Bis-trifluormethyl-4,4'-sulfonyl-di-anilin；Bis-(4-amino-2-trifluormethyl-phenyl)-sulfon；4-[4-Amino-2-(trifluoromethyl)phenyl]sulfonyl-3-(trifluoromethyl)aniline
• CAS: 384-36-1
• 化学式: C₁₄H₁₀F₆N₂O₂S
• 分子量: 384.302
• InChiKey: GSOYMUOHRTWIGJ-UHFFFAOYSA-N

物化性质

• 熔点：
  211-212 °C(Solv: water (7732-18-5); ethanol (64-17-5))
• 沸点：
  509.2±50.0 °C(Predicted)
• 密度：
  1.541±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  25
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  94.6
• 氢给体数：
  2
• 氢受体数：
  10

文献信息

• POLYAMIC ACID RESIN SOLUTION CONTAINING INTERPENETRATING POLYMER AND LAMINATE USING THE SAME
  申请人：WANG Tsung-Hsiung

  公开号：US20130171459A1

  公开（公告）日：2013-07-04

  Provided is a polyamic acid resin solution containing interpenetrating polymer. The solution includes a polyamic acid resin dissolved in a solvent. The polyamic acid resin includes an interpenetrating polymer formed of polyamic acid twining around hyper-branched polybismaleimide. The hyper-branched polybismaleimide includes a bismaleimide polymer, a bismaleimide oligomer, a barbituric acid-bismaleimide copolymer or combinations thereof.

  提供的是一种含有相互渗透聚合物的聚酰亚胺树脂溶液。该溶液包括在溶剂中溶解的聚酰亚胺树脂。聚酰亚胺树脂包括由聚酰亚胺绕绕着超支化聚双马来酰亚胺形成的相互渗透聚合物。超支化聚双马来酰亚胺包括双马来酰亚胺聚合物、双马来酰亚胺寡聚物、巴比妥酸-双马来酰亚胺共聚物或其组合。
• OPTICAL MEMBERS MADE OF POLYIMIDE RESINS
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1237015A1

  公开（公告）日：2002-09-04

  For providing a polyimide optical component exhibiting good physical properties inherent to a polyimide, i.e., heat resistance, mechanical properties, electric properties, thermal oxidation stability and chemical resistance, as well as good transparency and a high refractive index, this invention, this invention essentially uses a particular diamine and a particular tetracarboxylic dianhydride to give an optical component made of a polyimide having a motif represented by general formula (1):    wherein in general formula (1), A represents general formula (2), (3) or (4); X represents a direct bond, -O-, -SO2- or -C(CF3)2-; in general formula (2), R1 and R2 represent H, Cl, Br, CH3 or CF3; in general formula (3), A1 represents -O-, -S-, -CO-, -CH2-, -SO2-, -C(CH3)2- or -C(CF3)2-; in general formula (4), A2 represents a direct bond, -O-, -S-, -CO-, -SO2-, -C(CH3)2- or -C(CF3)2-.

  为了提供一种聚酰亚胺光学元件，使其具有聚酰亚胺固有的良好物理性能，即耐热性、机械性能、电性能、热氧化稳定性和耐化学性，以及良好的透明度和高折射率，本发明主要使用一种特定的二胺和一种特定的四羧酸二酐，以得到一种由具有通式（1）表示的图案的聚酰亚胺制成的光学元件： 其中，在通式（1）中，A 代表通式（2）、（3）或（4）；X 代表直接键、-O-、-SO2- 或-C(CF3)2-； 通式（2）中，R1 和 R2 代表 H、Cl、Br、CH3 或 ； 通式（3）中，A1 代表-O-、-S-、-CO-、-CH2-、-SO2-、-C( )2- 或-C( )2-； 通式（4）中，A2 代表直接键、-O-、-S-、-CO-、-SO2-、-C( )2- 或 -C( )2-。
• Low temperature polymide adhesive compositions and methods relating thereto
  申请人：E.I.Du Pont de Nemours and Company

  公开号：EP1424352A1

  公开（公告）日：2004-06-02

  The present invention relates to a polyimide adhesive composition having a polyimide derived from an aromatic dianhydride and a diamine component, where the diamine component is preferably about 50 to 90 mole % of an aliphatic diamine and about 10 to 50 mole % of an aromatic diamine. In one embodiment, the aliphatic diamine has the structural formula H2N-R-NH2 wherein R is hydrocarbon from C4 to C16 and the polyimide adhesive has a glass transition temperature in the range of from 150°C to 200°C. The present invention also relates to compositions comprising the polyimide adhesive of the present invention, including polyimide metal-clad laminate useful as flexible circuit when metal traces are formed out of the metal used in flexible, rigid, or flex-rigid circuit applications.

  本发明涉及一种聚酰亚胺粘合剂组合物，该组合物具有由芳香族二酐和二胺组分衍生的聚酰亚胺，其中二胺组分最好是约50至90摩尔％的脂肪族二胺和约10至50摩尔％的芳香族二胺。在一个实施方案中，脂肪族二胺的结构式为 H2N-R-NH2，其中 R 为 C4 至 C16 的烃，聚酰亚胺粘合剂的玻璃化转变温度为 150°C 至 200°C。 本发明还涉及包含本发明聚酰亚胺粘合剂的组合物，包括在柔性、刚性或挠性刚性电路应用中使用金属形成金属迹线时用作柔性电路的聚酰亚胺金属包覆层压板。
• High temperature polymeric materials containing corona resistant composite filler, and methods relating thereto
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP1484361A1

  公开（公告）日：2004-12-08

  Corona resistant, high temperature polymeric materials are disclosed which are generally useful in high voltage wire insulation or similar type applications. The materials contain composite fillers having an organic component with excellent dispersion properties in certain organic solvents, depending upon the particular embodiment selected, and an inorganic ceramic oxide component generally having excellent corona resistance properties.

  抗电晕高温聚合材料已被公开，通常可用于高压电线绝缘或类似应用。这些材料含有复合填料，其中的有机成分在某些有机溶剂中具有优异的分散性能，具体取决于所选的特定实施方案，而无机陶瓷氧化物成分通常具有优异的抗电晕性能。
• Dielectric substrate comprising a polyimide core layer and a high temperature fluoropolymer bonding layer, and methods relating thereto
  申请人：E.I. du Pont de Nemours and Company

  公开号：EP1498909A1

  公开（公告）日：2005-01-19

  An asymmetric multi-layer insulative film of improved internal adhesive strength is made by combining a layer of polyimide and a high-temperature bonding layer, the high-temperature bonding layer being derived from a high temperature base polymer made of poly(tetrafluoroethylene-co-perfluoro[alkyl vinyl ether]) (PFA) and optionally blended with from 0-60 weight percent poly(tetrafluoroethylene-co-hexafluoropropylene) (FEP). The polyimide and high-temperature bonding layer laminate optionally also contains a layer of unsintered, partially sintered, or totally sintered polytetrafluoroethylene (PTFE) bonded directly to the high-temperature bonding layer. In addition, the polyimide high-temperature bonding layer laminate may be adhered to a poly(tetrafluoroethylene-co-hexafluoropropylene) (FEP) adhesive primer layer to more effectively bond the polyimide core layer to the high-temperature bonding layer. This type of primer layer may also be used as a polyimide-to-metal bonding layer to assist bonding of the polyimide to a metal wire or metal layer.

  将一层聚酰亚胺和一层高温粘合层组合在一起，可制成一种具有更高内粘合强度的非对称多层绝缘膜，高温粘合层由聚四氟乙烯-全氟[烷基乙烯基醚]（PFA）制成的高温基础聚合物衍生而来，并可选择与 0-60 重量百分比的聚四氟乙烯-六氟丙烯（FEP）混合。聚酰亚胺和高温粘合层层压板还可选择包含一层未烧结、部分烧结或完全烧结的聚四氟乙烯（PTFE），直接粘合在高温粘合层上。此外，聚酰亚胺高温粘合层层压板可粘附在聚四氟乙烯-共六氟丙烯（FEP）粘合剂底层上，以更有效地将聚酰亚胺芯层粘合到高温粘合层上。这种底层也可用作聚酰亚胺与金属的粘合层，以帮助聚酰亚胺与金属丝或金属层粘合。