tetra-p-tolylantimony p-toluenesulfonate | 282525-89-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetra-p-tolylantimony p-toluenesulfonate
• 英文别名: tetra-p-tolylantimony 4-methylbenzenesulfonate；[tetrakis(4-methylphenyl)-λ5-stibanyl] 4-methylbenzenesulfonate
• CAS: 282525-89-7
• 化学式: C₃₅H₃₅O₃SSb
• 分子量: 657.477
• InChiKey: LDEOGUGHWYMNSI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.46
• 重原子数：
  40
• 可旋转键数：
  7
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  三氧化硫 、 penta(p-tolyl)antimony(V) 以 甲苯 为溶剂， 以72%的产率得到tetra-p-tolylantimony p-toluenesulfonate
  参考文献：
  名称：

  Sharutin, V. V.; Sharutina, O. K.; Platonova, T. P., Russian Journal of General Chemistry, 2000, vol. 70, # 11, p. 1820 - 1820

  摘要：

  DOI：

文献信息

• ——
  作者：V. V. Sharutin

  DOI：10.1023/a:1023667500059

  日期：——

  Tetra-p-tolylantimony 4-methylbenzenesulfonate (I) was synthesized via the reaction of tri-p-tolyl-bismuth bis(4-methylbenzenesulfonate) with penta-p-tolylantimony in toluene. According to the X-ray diffraction data, the antimony atoms of two individual molecules of I have a distorted trigonal bipyramidal coordination with the axial 4-methylbenzenesulfonate ligand and three equatorial tolyl ligands, one of which contains four carbon atoms disordered over two sites with the occupancy factors 0.7 and 0.3.
• ——
  作者：V. V. Sharutin

  DOI：10.1023/a:1023463212564

  日期：——

  Pentaarylantimony Ar3Sb (Ar = Ph, p-Tol) arylates diarylbismuth arylsulfonates Ar2BiOSO2Ar' (Ar' = C6H4Me-4; C6H3Me2-2,4, C6H3Me2-2,5) in ether at 20 degreesC (48 h) to form triarylbismuth in yields of up to 95%. The second reaction product is tetraarylantimony arenesulfonate. The reaction of pentaphenylantimony with phenylbismuth bis(arenesulfonate) PhBi(OSO2Ar')(2) under the same conditions leads to formation of diphenylbismuth arenesulfonate and tetraphenylantimony arenesulfonate in yields of up to 90%.
• Sharutin; Sharutina; Tarasova, Russian Journal of General Chemistry, 1999, vol. 69, # 12, p. 1892 - 1894
  作者：Sharutin、Sharutina、Tarasova、Kharsika、Bel'skii

  DOI：——

  日期：——