cis-bis(N,N-diethyl-N'-furoylthioureato)cobalt(II) | 1364441-84-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: cis-bis(N,N-diethyl-N'-furoylthioureato)cobalt(II)
• CAS: 1364441-84-8
• 化学式: C₂₀H₂₆CoN₄O₄S₂
• 分子量: 509.576
• InChiKey: GKQTYBBNDUURRZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cobalt(II) diacetate tetrahydrate 、 1-furoyl-3,3-diethylthiourea 在 NaOH 作用下， 以 乙醇 为溶剂， 以76%的产率得到cis-bis(N,N-diethyl-N'-furoylthioureato)cobalt(II)
  参考文献：
  名称：

  Synthesis and structural characterization of cobalt(II) and copper(II) complexes with N,N-disubstituted-N′-acylthioureas

  摘要：

  A new complexes of Co(II) and Cu(II) with N,N-disubstituted-N'-acylthioureas have been prepared and characterized by elemental analysis, and spectroscopic techniques. The structure of N,N-diethyl-N'-furoylthiourea and Co(II) complexes with N,N-diethyl-N'-furoyl- and N,N-diethyl-N'-benzoylthiourea were determined by X-ray crystallography. The structural data reveal that the acylthiourea moiety adopts a cis conformation in the crystal and the complexes show a slightly distorted square-planar geometry. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.02.008