tetraphenyl-1,4,9,13 tetraoxo-1,4,9,13 tetraphospha-1,4,9,13 cyclohexadecane | 57978-08-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetraphenyl-1,4,9,13 tetraoxo-1,4,9,13 tetraphospha-1,4,9,13 cyclohexadecane
• 英文别名: 1,5,9,13-tetraphenyl-1,5,9,13-tetraphospha-cyclohexadecane 1,5,9,13-tetraoxide；tetra-P-phenyl-[16]ane-P₄ tetra-P-oxide；1,5,9,13-Tetraphenyl-1lambda5,5lambda5,9lambda5,13lambda5-tetraphosphacyclohexadecane 1,5,9,13-tetraoxide；1,5,9,13-tetraphenyl-1λ5,5λ5,9λ5,13λ5-tetraphosphacyclohexadecane 1,5,9,13-tetraoxide
• CAS: 57978-08-2
• 化学式: C₃₆H₄₄O₄P₄
• 分子量: 664.638
• InChiKey: CIFZXROWTRWENW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  44
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  68.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,3-双(苯基膦酰)丙烷 在 sodium hydroxide 、 偶氮二异丁腈 、 溴 作用下， 以 乙醇 、 二氯甲烷 、 甲苯 为溶剂， 反应 156.0h， 生成 tetraphenyl-1,4,9,13 tetraoxo-1,4,9,13 tetraphospha-1,4,9,13 cyclohexadecane
  参考文献：
  名称：

  Synthese de tetra oxydes de phosphine macrocycliques a partir des bisphosphoniums bis oxydes de phosphine correspondants

  摘要：

  Macrocyclisation of halogenated phosphine dioxides with bis (diphenylphosphino)-1,3 propane yields new bifunctionnal macrocycles 4, 5 with 4 phosphorus atoms in the ring. Application of a new methodology, via a bridge protection leads after an alkaline hydrolysis to homologous phosphine tetra oxides in good yields. Macrocyclic phosphine polyoxides with a two carbon bridging unit between the phosphorus atoms, a system difficult to prepare by other methods, can be obtained satisfactorily.

  DOI：

  10.1016/s0040-4020(01)90498-3

文献信息

• VINCENA, M.;GRIMALDO-MORON, J. T.;VIDAL, M., TETRAHEDRON, 47,(1991) N, C. 403-410
  作者：VINCENA, M.、GRIMALDO-MORON, J. T.、VIDAL, M.

  DOI：——

  日期：——
• Fluorescent complex and lighting system using the same
  申请人：Iwanaga Hiroki

  公开号：US20070007884A1

  公开（公告）日：2007-01-11

  Disclosed are a fluorescent complex comprising a rare earth atom and a ligand having a structure comprising a plurality of coordinating groups bonded to each other in a ring form, and a lighting system and a flashlight device using the same. This fluorescent complex can realize high-intensity fluorescence and a prolonged service life and gives a sharp fluorescence spectrum.
• FLUORESCENT COMPLEX AND LIGHTING SYSTEM USING THE SAME
  申请人：Iwanaga Hiroki

  公开号：US20080001515A1

  公开（公告）日：2008-01-03

  This invention provides a fluorescent complex possessing excellent durability and luminous intensity, and a lighting system utilizing the same. The fluorescent complex comprises a rare earth ion and a β-diketone ligand. In the fluorescent complex, the β-diketone ligand comprises a β-diketone skeleton, a fluoroalkyl group, and an electron donative linking group for linking the β-diketone skeleton to the fluoroalkyl group. The fluorescent complex can be utilized in a lighting system. The rare earth ion is preferably a lanthanoid ion, particularly preferably a europium or terbium ion. When the β-diketone ligand further comprises an aromatic group, the luminous intensity can be further improved.
• US7902741B2
  申请人：——

  公开号：US7902741B2

  公开（公告）日：2011-03-08
• Synthese de tetra oxydes de phosphine macrocycliques a partir des bisphosphoniums bis oxydes de phosphine correspondants
  作者：M. Vincens、J.T. Grimaldo-Morön、M. Vidal

  DOI：10.1016/s0040-4020(01)90498-3

  日期：1991.1

  Macrocyclisation of halogenated phosphine dioxides with bis (diphenylphosphino)-1,3 propane yields new bifunctionnal macrocycles 4, 5 with 4 phosphorus atoms in the ring. Application of a new methodology, via a bridge protection leads after an alkaline hydrolysis to homologous phosphine tetra oxides in good yields. Macrocyclic phosphine polyoxides with a two carbon bridging unit between the phosphorus atoms, a system difficult to prepare by other methods, can be obtained satisfactorily.