[Rh(N3)2(1-ethyl-2-(p-tolylazo)imidazole)2](ClO4) | 1414975-20-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Rh(N3)2(1-ethyl-2-(p-tolylazo)imidazole)2](ClO4)
• 英文别名: [Rh(N3)2(MeaaiEt)2](ClO4)
• CAS: 1414975-20-4
• 化学式: C₂₄H₂₈N₁₄Rh*ClO₄
• 分子量: 714.936
• InChiKey: NWAIAPCIYZLZSO-HVRXRLAPSA-M

反应信息

• 作为产物：
  描述：

  sodium azide 、 cis-[Rh(Cl)2(1-ethyl-2-(p-tolylazo)imidazole)2](ClO4) 、 sodium perchlorate 在 silver nitrate 作用下， 以 水 、 乙腈 为溶剂， 反应 3.5h， 生成 [Rh(N3)2(1-ethyl-2-(p-tolylazo)imidazole)2](ClO4)
  参考文献：
  名称：

  Synthesis, structure, DNA interaction and nuclease activity of rhodium(III)–arylazoimidazole complexes

  摘要：

  The Rh(III) complexes of 1-alkyl-2-(arylazo)imidazoles (RaaiR'), [Rh(X)(2)(RaaiR')(2)](ClO4) (R = H (1, 3), Me (2, 4); R' = Me (a), Et (b), CH2Ph (c); X = Cl (1, 2), N-3 (3, 4)), are synthesized and characterized by spectral (IR, UV-Vis, Mass and H-1 NMR) data. The structural confirmation has been done by single crystal X-ray diffraction study of [RhCl2(MeaaiEt)(2)]ClO4 (2b) (MeaaiEt, 1-ethyl-2-(p-tolylazo) imidazole). The DNA binding of the complexes (binding constant: 0.86 x 10(4) to 1.05 x 10(5)) have been examined by absorption and fluorescence spectroscopic measurements. The nuclease activity of the complexes are examined by gel-electrophoresis and has revealed the highest activity of [Rh(N-3)(2)(RaaiR')(2)]ClO4. The DFT computation has been performed to the optimized geometry of the complexes to interpret the electronic structures and their spectral properties. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.08.005