Ti(acetylacetonate)(palmitate)(OC6H4CHNC6H4Cl)2 | 1279096-74-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Ti(acetylacetonate)(palmitate)(OC6H4CHNC6H4Cl)2
• 英文别名: Ti(acac)(OOCC15H31)(OC6H4CHNC6H4Cl)2
• CAS: 1279096-74-0
• 化学式: C₄₇H₅₆Cl₂N₂O₆Ti
• 分子量: 863.757
• InChiKey: RRJMZBMYTSXJRF-UZAQZMKHSA-K

反应信息

• 作为产物：
  描述：

  Ti(acetylacetonate)(chloride)2(palmitate) 、 以 苯 为溶剂， 以83%的产率得到Ti(acetylacetonate)(palmitate)(OC6H4CHNC6H4Cl)2
  参考文献：
  名称：

  Shape Controlled Synthesis of Nano-Sized Titanium(IV) Metal-Organic Frameworks

  摘要：

  A convenient method to synthesize shape controlled nano-sized metal-organic frameworks (MOFs) has been explored to prepare some novel mixed-ligand complexes of titanium(IV) with the general formula [Ti(acac)Cl2-n(OOCC15H31)(SB)n] (where Hacac = acetylacetone, HSB = Schiff bases and n = 1 or 2). They have been synthesized by stepwise substitutions of chloride ions from titanium(IV) chloride. The complexes were characterized by elemental analyses, molecular weight determinations, spectral, and TEM studies. Coordination number 7 and 8 was assigned for titanium(IV) in the complexes. The powder XRD, TEM, and SAED studies indicates that these complexes are nano-sized having poor crystalline nature.

  DOI：

  10.1080/15533174.2010.538026