tetra-α-(2,2,4-trimethyl-3-pentoxy)phthalocyaninatocobalt | 879296-83-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: tetra-α-(2,2,4-trimethyl-3-pentoxy)phthalocyaninatocobalt
• CAS: 879296-83-0
• 化学式: C₆₄H₈₀CoN₈O₄
• 分子量: 1084.38
• InChiKey: CEZOFQIOYOVEMW-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  tetra-α-(2,2,4-trimethyl-3-pentoxy)phthalocyaninatocobalt 、 三氟乙酸 以 甲苯 为溶剂， 生成 [tetra-α-(2,2,4-trimethyl-3-pentoxy)phthalocyaninatocobalt](+1H)
  参考文献：
  名称：

  The effect of protonation on the spectra and stabilities of alkoxyl substituted phthalocyaninatometals

  摘要：

  The protonation abilities of phthalocyaninatometals (MPcs) increase but their stabilities reduce by the introduction of alkoxyl substituents at alpha position. In the toluene, the order of mono-protonation rate for the tetra-alpha-(2, 2, 4-trimethyl-3-pentoxy)phthalocyaninatometals sorts with the center metals is Zn > Co > Cu > Ni > Fe, which is opposite to the order of their wavelength difference between the Q bands and X bands. However, their mono-protonated species can be decomposed easily at the rate order FePc > CoPc > CuPc > NiPc > ZnPc, analogous to their decomposition abilities in the benzoylperoxide (BPO) oxidation. In addition, it is interesting that a more remarkable decomposition is found when partial CuPc was mono-protonated. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2008.03.020