[(Z)-[amino(phenyl)methylidene]amino] 2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptanimidate | 146304-61-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(Z)-[amino(phenyl)methylidene]amino] 2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptanimidate
• CAS: 146304-61-2
• 化学式: C₁₄H₈F₁₃N₃O
• 分子量: 481.216
• InChiKey: PZNFGRVUCIGGHF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  31
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  71.5
• 氢给体数：
  2
• 氢受体数：
  16

反应信息

• 作为反应物：
  描述：

  [(Z)-[amino(phenyl)methylidene]amino] 2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptanimidate 在 吡啶 、 difluoro-{1,1,2,2-tetrafluoro-2-[1,1,2,2-tetrafluoro-2-(1,1,2,2-tetrafluoro-2-trifluoromethoxy-ethoxy)-ethoxy]-ethoxy}-acetyl fluoride 作用下， 反应 2.0h， 以99%的产率得到5-perfluorohexyl-3-phenyl-1,2,4-oxadiazole
  参考文献：
  名称：

  Reaction of perfluorinated nitriles with benz-and terephthalamidoximes for the isolation of mixed 1,2,4-oxadiazoles

  摘要：

  The reaction of perfluorinated nitriles with benz- and terephthalamidoximes afforded amidoximimidates which can form mixed 1,2,4-oxadiazoles in high yield under mild conditions by the action of acid fluorides of perfluorocarboxylic acids. The structure of the compounds obtained was confirmed by the methods of C-13, F-19, and H-1 NMR, and by IR spectroscopy.

  DOI：

  10.1007/bf00864345
• 作为产物：
  描述：

  全氟庚腈 、 苯甲酰胺肟 以 乙醚 为溶剂， 反应 1.0h， 以99%的产率得到[(Z)-[amino(phenyl)methylidene]amino] 2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptanimidate
  参考文献：
  名称：

  Reaction of perfluorinated nitriles with benz-and terephthalamidoximes for the isolation of mixed 1,2,4-oxadiazoles

  摘要：

  The reaction of perfluorinated nitriles with benz- and terephthalamidoximes afforded amidoximimidates which can form mixed 1,2,4-oxadiazoles in high yield under mild conditions by the action of acid fluorides of perfluorocarboxylic acids. The structure of the compounds obtained was confirmed by the methods of C-13, F-19, and H-1 NMR, and by IR spectroscopy.

  DOI：

  10.1007/bf00864345

文献信息

• Reaction of perfluorinated nitriles with benz-and terephthalamidoximes for the isolation of mixed 1,2,4-oxadiazoles
  作者：E. V. Kabakchi、V. V. Il'in、A. V. Ignatenko、V. A. Ponomarenko

  DOI：10.1007/bf00864345

  日期：1992.8

  The reaction of perfluorinated nitriles with benz- and terephthalamidoximes afforded amidoximimidates which can form mixed 1,2,4-oxadiazoles in high yield under mild conditions by the action of acid fluorides of perfluorocarboxylic acids. The structure of the compounds obtained was confirmed by the methods of C-13, F-19, and H-1 NMR, and by IR spectroscopy.