[Ni(dppe)2]Br | 1240788-72-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ni(dppe)2]Br
• CAS: 1240788-72-0
• 化学式: Br*C₅₂H₄₈NiP₄
• 分子量: 935.442
• InChiKey: AFRGXDUINZJOBT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  7.51
• 重原子数：
  58.0
• 可旋转键数：
  8.0
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  Ni(II)(Phpy)2 、 溴 、 1,2-双(二苯基膦)乙烷 以 苯 为溶剂， 以7%的产率得到[Ni(dppe)2]Br
  参考文献：
  名称：

  Synthesis and Reactivity of Ni^II(Phpy)₂ (Phpy = 2-Phenylpyridine)

  摘要：

  This article describes the synthesis and reactivity of Ni-II(Phpy)(2) (Phpy = 2-phenylpyridine) with a variety of oxidants, including O-2, Br-2, PhICl2, N-fluoropyridinium salts, Cu-II salts, and N-halosuccinimides. High-oxidation-state Ni intermediates were not detected in any of these transformations. In all cases, the major organic product resulted from oxidatively induced C C bond formation to generate the Phpy Phpy dimer. Traces (2-16%) of organic products resulting from C-O, C-Br, C-Cl, and C-N bond-forming reductive elimination were also observed.

  DOI：

  10.1021/om100387z