β-Chlorostyrolchlorid | 6124-68-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: β-Chlorostyrolchlorid
• 英文别名: 2-Chlor-3-phenyl-oxiran；β-Chlorostyroloxid；Chlorostyrene oxide；2-chloro-3-phenyloxirane
• CAS: 6124-68-1
• 化学式: C₈H₇ClO
• 分子量: 154.596
• InChiKey: KUZMSPAMAHVVKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• SILVER-CERIUM OXIDE COMPOSITE CATALYST SUPPORTED ON AN ALKALINE CARRIER AND METHOD FOR PRODUCING THE SAME
  申请人：OSAKA UNIVERSITY

  公开号：US20160310931A1

  公开（公告）日：2016-10-27

  Conventionally, a silver-cerium oxide composite containing a silver particle and cerium oxide covering the surface of the silver particle has been synthesized through a multi-stage process, and is disadvantageous not only in that there is a need to use an organic solvent and a surfactant, causing the time and cost to be increased, but also in that there is a possiblity that fulminating silver is formed, leading to a problem about the safety. A method for producing a catalyst having a silver-cerium oxide composite and an alkaline carrier having supported thereon the oxide composite, the silver-cerium oxide composite containing a silver particle and cerium oxide covering the surface of the silver particle, the method having preparing a mixture containing a silver compound, a cerium compound, and an alkaline carrier, and drying the mixture is provided.

  传统上，通过多阶段工艺合成了含有银颗粒和覆盖在银颗粒表面的氧化铈的银-氧化铈复合材料，不仅存在需要使用有机溶剂和表面活性剂的缺点，导致时间和成本增加，而且可能形成易爆银，存在安全问题。提供了一种生产具有银-氧化铈复合材料和在其上支撑氧化物复合物的碱性载体的催化剂的方法，其中银-氧化铈复合材料包含银颗粒和覆盖在银颗粒表面的氧化铈，该方法包括制备含有银化合物、氧化铈化合物和碱性载体的混合物，并将混合物干燥。
• Enzymatic conversion of epoxides
  申请人：Rijksuniversiteit Groningen

  公开号：US20030124693A1

  公开（公告）日：2003-07-03

  The invention relates to a process for converting an epoxide to an alcohol. The process according to the invention is enzymatically catalyzed and highly enantioselective and regiospecific.

  本发明涉及一种将环氧化物转化为醇的方法。本发明的方法是通过酶催化反应实现的，具有高度对映选择性和区域特异性。
• Process For the Production of an Optically Enriched Tertiary Alcohol
  申请人：Hauer Bernhard

  公开号：US20080299626A1

  公开（公告）日：2008-12-04

  A process for the production of an optically enriched tertiary alcohol of the formula (2a) or (2b), by reacting an epoxide of the formula (1) with a nucleophilic agent Nu in the presence of halohydrin dehalogenase.

  一种生产光学纯的三级醇的方法，其化学式为(2a)或(2b)，包括在卤水醇脱卤酶存在下，通过将化学式为(1)的环氧化合物与亲核试剂Nu反应。
• 3-substituted-alpha,beta-dibromoethylbenzene and process for preparing the same
  申请人：Mitsubishi Chemical Corporation

  公开号：EP0754665A2

  公开（公告）日：1997-01-22

  A novel 3-substituted α,β-dibromoethylbenzene of formula (I): wherein X represents a halogen atom or a trihalomethyl group, which is a useful intermediate for pharmaceuticals or agricultural chemicals, is prepared by a simple and high yield process which comprises reacting a 3-substituted α-bromoethylbenzene represented by formula (II): wherein X is as defined above, or a 3-substituted ethylbenzene represented by formula (III): wherein X is as defined above, with bromine in the presence of a quaternary ammonium salt.

  一种新型 3-取代α，β-二溴乙基苯，其式为(I)： 其中 X 代表卤素原子或三卤甲基，是一种有用的医药或农药中间体，其制备方法简单且收率高，包括将式（II）代表的 3-取代α-溴乙苯与式（I）代表的 3-取代α,β-二溴乙苯反应： 其中 X 如上定义、 或式 (III) 所代表的 3-取代乙基苯： 其中 X 如上定义，在季铵盐存在下与溴反应。
• Organic electroluminescent materials and devices
  申请人：Universal Display Corporation

  公开号：US10230060B2

  公开（公告）日：2019-03-12

  Electronic displays including organic light emitting diodes having an organic layer including a compound including a ligand having the formula: is disclosed. In these formulas, each R1, R2, and R3 is independently selected from hydrogen, alkyl, and aryl; at least one of R1 and R2 is a branched alkyl containing at least 4 carbon atoms, where the branching occurs at a position further than the benzylic position; where R1 and R3 are mono-, di-, tri-, tetra-, or no substitutions; and R2 is mono-, di-, or no substitutions. Emissive layers including a host material doped with these heteroleptic iridium complexes are also disclosed.

  包括有机发光二极管在内的电子显示器，其有机层包括一种化合物，该化合物包括具有以下式子的配位体： 的化合物的电子显示器。在这些式子中，每个 R1、R2 和 R3 都独立地选自氢、烷基和芳基；R1 和 R2 中至少有一个是含有至少 4 个碳原子的支化烷基，其中支化发生在比苄基位置更远的位置；其中 R1 和 R3 是单取代、二取代、三取代、四取代或无取代；R2 是单取代、二取代或无取代。此外，还公开了包括掺杂了这些杂环铱络合物的主材料的发射层。