1-(1H-pyrrol-2-yl)-N-[2-[2-[2-(1H-pyrrol-2-ylmethylideneamino)phenyl]sulfanylethylsulfanyl]phenyl]methanimine | 1239919-37-9

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 1-(1H-pyrrol-2-yl)-N-[2-[2-[2-(1H-pyrrol-2-ylmethylideneamino)phenyl]sulfanylethylsulfanyl]phenyl]methanimine
• CAS: 1239919-37-9
• 化学式: C₂₄H₂₂N₄S₂
• 分子量: 430.597
• InChiKey: FMSCXYNAPBXIMC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  30
• 可旋转键数：
  9
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  107
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-吡咯甲醛 、 2,2-(乙烯二硫代)二苯胺 以 乙醇 为溶剂， 反应 5.17h， 以51%的产率得到1-(1H-pyrrol-2-yl)-N-[2-[2-[2-(1H-pyrrol-2-ylmethylideneamino)phenyl]sulfanylethylsulfanyl]phenyl]methanimine
  参考文献：
  名称：

  Synthesis and Characterization of New Schiff Bases 2-(2-(2-(Aryl)Methyleneamino)Phenylthio) Ethylthio)-N-((aryl)Methylene)Benzeneamine

  摘要：

  A series of Schiff bases containing four to six coordination sites N2S2 X2(X = O,N) 2-(2-(2-(aryl)methyleneamino)phenylthio)ethylthio)-N-((aryl)methylene)benzeneamine (2c-f) were prepared from the reaction of 1,2-di(2-aminophenylthio)ethane (1) with aromatic aldehydes. All compounds were characterized by means IR, mass, 1H and 13C NMR spectroscopy, and elemental analysis, and in the case of 2b with a single crystal X-ray diffraction. The X-ray crystal structure of 2b showed that the resonance occurs between aromatic rings, through the C=N bonds of the molecule. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.

  DOI：

  10.1080/10426500903107930