| 1497449-03-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1497449-03-2
• 化学式: C₃₄H₄₁NO₂Ti
• 分子量: 543.585
• InChiKey: NHLRZCOAAUIZPO-ZTVVKIFVSA-M

反应信息

• 作为反应物：
  描述：

  、 三(五氟苯基)硼烷 以 氘代苯 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Highly Selective Olefin Trimerization Catalysis by a Borane-Activated Titanium Trimethyl Complex

  摘要：

  Reaction of a trimethyl titanium complex, (FI)TiMe3 (FI = phenoxy-imine), with 1 equiv of B(C6F5)(3) gives [(FI)TiMe2][MeB(C6F5)(3)], an effective precatalyst for the selective trimerization of ethylene. Mechanistic studies indicate that catalyst initiation involves generation of an active Ti-II species by olefin insertion into a Ti-Me bond, followed by beta-H elimination and reductive elimination of methane, and that initiation is slow relative to trimerization. (FI)TiMe3/B(C6F5)(3) also leads to a competent catalyst for the oligomerization of alpha-olefins, displaying high selectivity for trimers (>95%), approximately 85% of which are one regioisomer. This catalyst system thus shows promise for selectively converting light a-olefins into transportation fuels and lubricants.

  DOI：

  10.1021/om401098m
• 作为产物：
  描述：

  、 甲基溴化镁 以 1,4-二氧六环 、 乙醚 为溶剂， 反应 2.0h， 以26%的产率得到
  参考文献：
  名称：

  Highly Selective Olefin Trimerization Catalysis by a Borane-Activated Titanium Trimethyl Complex

  摘要：

  Reaction of a trimethyl titanium complex, (FI)TiMe3 (FI = phenoxy-imine), with 1 equiv of B(C6F5)(3) gives [(FI)TiMe2][MeB(C6F5)(3)], an effective precatalyst for the selective trimerization of ethylene. Mechanistic studies indicate that catalyst initiation involves generation of an active Ti-II species by olefin insertion into a Ti-Me bond, followed by beta-H elimination and reductive elimination of methane, and that initiation is slow relative to trimerization. (FI)TiMe3/B(C6F5)(3) also leads to a competent catalyst for the oligomerization of alpha-olefins, displaying high selectivity for trimers (>95%), approximately 85% of which are one regioisomer. This catalyst system thus shows promise for selectively converting light a-olefins into transportation fuels and lubricants.

  DOI：

  10.1021/om401098m