[Cu(II)(N,N'-bis(2-hydroxybenzyl)-1,3-bis[(2-aminoethyl) amino]-2-propanol)Cl]ClO4*CH3OH*H2O | 844444-12-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cu(II)(N,N'-bis(2-hydroxybenzyl)-1,3-bis[(2-aminoethyl) amino]-2-propanol)Cl]ClO4*CH3OH*H2O
• CAS: 844444-12-8
• 化学式: CH₄O*C₂₁H₃₂N₄O₃*ClO₄*Cl*Cu*H₂O
• 分子量: 637.017
• InChiKey: FYDKUPQYZAZXEB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 copper(II) perchlorate hexahydrate 、 N,N'-bis(2-hydroxybenzyl)-1,3-bis[(2-aminoethyl)amino]-2-propanol tetrahydrochloride 、 水 在 NaOH 作用下， 以 甲醇 、 水 为溶剂， 以11%的产率得到[Cu(II)(N,N'-bis(2-hydroxybenzyl)-1,3-bis[(2-aminoethyl) amino]-2-propanol)Cl]ClO4*CH3OH*H2O
  参考文献：
  名称：

  Supramolecular structures of Co(III) and Cu(II) complexes of a novel alcohol and phenol containing polyamine ligand H2L (H2L=N,N′-bis(2-hydroxybenzyl)-1,3-bis[(2-aminoethyl)amino]-2-propanol)

  摘要：

  A novel alcohol and phenol containing polyamine ligand H2L (HL = N',N'-bis[(2-hydroxybenzyl)-1.3-bis(2-aminoethyl) amino]-2-propanol) and its Co-(III) and C-(II) complexes, [CoL]ClO4 (1) and [Cu(H2L)Cl]ClO4 . CH3OH . H2O (2) have been synthesized and characterized. Single crystal X-ray diffraction analyses indicate that both of the complexes are mononuclear. The Co-(III) center in complex 1 has a distorted octahedral geometry, with four N atoms of L2- situated in the equatorial plane, and two deprotonated phenoxo O atoms strongly coordinated at the axial positions. Along the c-axis, the [CoL](+) cations are connected alternatively by double ClO4- and double alkoxyl hydrogen-bonding bridges, affording a 1D supramolecular structure. In 2, the Cu-(II) center has a similar coordination geometry, whereas the axial positions are weakly coordinated by Cl- and a protonated phenolic O atom. Approximately along the ab-plane, a 2D structure is assembled via multiple hydrogen bonds involving the alkoxyl, phenoxyl. amino. Cl- and the lattice water molecules. In this work, the structures of the supramolecular coordination assemblies are shown to be tuned by various factors, such as the donor sets of the ligands, the central metal atoms and the counteranions. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.11.009