[PdMe(CD2Cl2)(N,N,N',N'-tetramethylethylenediamine)][BMe(C6F5)3] | 208036-82-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [PdMe(CD2Cl2)(N,N,N',N'-tetramethylethylenediamine)][BMe(C6F5)3]
• CAS: 208036-82-2
• 化学式: CH₃*CH₂Cl₂*C₆H₁₆N₂*C₁₉H₃BF₁₅*Pd
• 分子量: 851.598
• InChiKey: NHOPJKHKVSTEHG-DYXLTBOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.85
• 重原子数：
  48.0
• 可旋转键数：
  6.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  6.48
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  乙烯 、 [PdMe(CD2Cl2)(N,N,N',N'-tetramethylethylenediamine)][BMe(C6F5)3] 以 二氯甲烷-D2 为溶剂， 生成 [PdMe(ethylene)(N,N,N',N'-tetramethylethylenediamine)](1+)
  参考文献：
  名称：

  Nature of the Initiation, Propagation, and Chain Transfer Steps during the Formation of Ethylene Oligomers Catalyzed by PdMe₂(N,N,N‘N‘-tetramethylethylenediamine)/B(C₆F₅)₃

  摘要：

  Reaction of equimolar quantities of PdMe2(Me2NCH2CH2NMe2) and B(C6F5)(3) in the presence of ethylene results in the formation of [PdMe(C2H4)(Me2NCH2CH2NMe2)](+)[BMe(C6F5)(3)](-); the latter catalyzes the oligomerization of ethylene to highly branched products, which are apparently formed via both reversible beta-elimination-reinsertion processes and the incorporation of short chain oligomeric products.

  DOI：

  10.1021/om971060p
• 作为产物：
  描述：

  (N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II) 、 三(五氟苯基)硼烷 以 二氯甲烷-D2 为溶剂， 生成 [PdMe(CD2Cl2)(N,N,N',N'-tetramethylethylenediamine)][BMe(C6F5)3]
  参考文献：
  名称：

  Nature of the Initiation, Propagation, and Chain Transfer Steps during the Formation of Ethylene Oligomers Catalyzed by PdMe₂(N,N,N‘N‘-tetramethylethylenediamine)/B(C₆F₅)₃

  摘要：

  Reaction of equimolar quantities of PdMe2(Me2NCH2CH2NMe2) and B(C6F5)(3) in the presence of ethylene results in the formation of [PdMe(C2H4)(Me2NCH2CH2NMe2)](+)[BMe(C6F5)(3)](-); the latter catalyzes the oligomerization of ethylene to highly branched products, which are apparently formed via both reversible beta-elimination-reinsertion processes and the incorporation of short chain oligomeric products.

  DOI：

  10.1021/om971060p