meso,meso'-bis(octaethylporphyrinyl)butadiyne, dinickel complex | 67168-57-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: meso,meso'-bis(octaethylporphyrinyl)butadiyne, dinickel complex
• CAS: 67168-57-4
• 化学式: C₇₆H₈₆N₈Ni₂
• 分子量: 1228.95
• InChiKey: RDLOTVSOTITHOV-MDQBWAKOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  meso,meso'-bis(octaethylporphyrinyl)butadiyne, dinickel complex 、 zinc diacetate 生成
  参考文献：
  名称：

  Arnold, Dennis P.; Heath, Graham A., Journal of the American Chemical Society, 1993, vol. 115, # 25, p. 12197 - 12198

  摘要：

  DOI：
• 作为产物：
  描述：

  bis(acetylacetonate)nickel(II) 、 以 氯仿 为溶剂， 生成 meso,meso'-bis(octaethylporphyrinyl)butadiyne, dinickel complex
  参考文献：
  名称：

  Arnold, Dennis P.; Heath, Graham A., Journal of the American Chemical Society, 1993, vol. 115, # 25, p. 12197 - 12198

  摘要：

  DOI：

文献信息

• Orientation and Substituent Effects on the Properties of the Diacetylene-Group Connected Octaethylporphyrin–Dihexylbithiophene Derivatives (OEP–DHBTh–X) Carrying Electron-Withdrawing Groups
  作者：Naoto Hayashi、Takashi Nishihara、Takuya Matsukihira、Hiroki Nakashima、Keiko Miyabayashi、Mikio Miyake、Hiroyuki Higuchi

  DOI：10.1246/bcsj.80.371

  日期：2007.1.15

  Orientational isomers of the octaethylporphyrin–dihexylbithiophene (OEP–DHBTh) derivatives connected with a diacetylene linkage were synthesized, with various electron-withdrawing substituents X attached at the ends. The effects of DHBTh orientation and X substituent on the properties of OEP–DHBTh–X (X = H, Br, CN, CHO, and NO2) were studied and compared with those of related OEP derivatives.

  合成了连接有二炔基链的八乙基卟啉-二己基二噻苯（OEP-DHBTh）异构体，末端附有不同的电子吸引取代基X。研究了DHBTh方向和X取代基对OEP-DHBTh-X（X = H, Br, CN, CHO和NO2）性质的影响，并与相关OEP衍生物进行了比较。
• Synthesis and Properties of Head-to-head, Head-to-tail, and Tail-to-tail Orientational Isomers of Extended Dihexylbithiophene–Octaethylporphyrin System [OEP–(DHBT)_<i>n</i>–OEP] Connected with 1,3-Butadiyne Linkages
  作者：Hiroyuki Higuchi、Takashi Ishikura、Kazumine Mori、Yukari Takayama、Koji Yamamoto、Keita Tani、Keiko Miyabayashi、Mikio Miyake

  DOI：10.1246/bcsj.74.889

  日期：2001.5

  An extended π-electronic conjugation system of dihexylbithiophene–octaethylporphyrin [OEP–(DHBT)n–OEP; n = 1–5], all the chromophores in which are connected with the linkage of 1,3-butadiyne (diacetylene), was synthesized by an oxidative cross-coupling reaction of the corresponding terminal acetylenes. Absorption spectral and electrochemical properties of the OEP–(DHBT)n–OEP system were examined. The results proved that the orientation of two 3-hexylthiophene (3HTh) rings of DHBT plays an important role in electronic communications between the two terminal OEP rings.

  二己基联噻吩-八乙基卟啉的扩展 π 电子共轭体系 [OEP-(DHBT)n-OEP； n = 1–5]，其中所有发色团均与 1,3-丁二炔（丁二炔）键连接，通过相应末端乙炔的氧化交叉偶联反应合成。检查了 OEP-(DHBT)n-OEP 系统的吸收光谱和电化学性质。结果证明DHBT的两个3-己基噻吩(3HTh)环的取向在两个末端OEP环之间的电子通信中起着重要作用。
• Enormously extended π-electronic conjugation system of dimeric octaethylporphyrin transmitted with anthracene
  作者：Hideto Kempe、Natsuki Kuroda、Junro Yoshino、Naoto Hayashi、Hiroyuki Higuchi

  DOI：10.1016/j.tetlet.2014.07.045

  日期：2014.9
• Supramolecular Chirogenesis in Weakly Interacting Hosts:  Role of the Temperature, Structural, and Electronic Factors in Enhancement of Chiroptical Sensitivity
  作者：Victor Borovkov、Takuro Yamamoto、Hiroyuki Higuchi、Yoshihisa Inoue

  DOI：10.1021/ol800179c

  日期：2008.3.1

  A new supramolecular chirogenic system on the basis of tetrakis(nickel porphyrin) and various enantiopure solvents, which was specifically designed for investigation of the chirogenic phenomenon upon extremely weak interaction modes and marginal chiroptical responses, is reported. The temperature was found to be a key factor controlling the chirality transfer process in these assemblies.