Tris(2,5-ditertiary butyl-4-hydroxy phenyl) phosphite | 21729-63-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Tris(2,5-ditertiary butyl-4-hydroxy phenyl) phosphite
• 英文别名: Tris(2,5-ditert-butyl-4-hydroxyphenyl) phosphite
• CAS: 21729-63-5
• 化学式: C₄₂H₆₃O₆P
• 分子量: 694.932
• InChiKey: RITMCSKITUMWCK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.5
• 重原子数：
  49
• 可旋转键数：
  12
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  88.4
• 氢给体数：
  3
• 氢受体数：
  6

文献信息

• 2,6-Di-tertiary butyl phenyl pentaerythritol spiro bis-phosphites enhancing the stability to heat and light of synthetic resins, stabilizer compositions comprising phenolic antioxidants and such phosphites, and synthetic resin compositions containing the same
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0038876A1

  公开（公告）日：1981-11-04

  2,6-Di-tertiary butyl phenyl pentaerythritol spiro bis-phosphites are provided having the structure: wherein: R is alkyl having from one to six carbon atoms; R is methyl or ethyl; R2 is selected from the group consisting of alkyl having from one up to about eighteen carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; and alkaryl and aryl having from six to about thirty carbon atoms; such groups substituted with from one to about four oxy ether-0- and/or carboxylic ester-COO-groups; the residue of a polyhydric alcohol having from two to about eighteen carbon atoms, and from two to about ten hydroxyl groups; and the residue of a polyphenol having from six to about eighteen carbon atoms and from two to about ten phenolic hydroxyl groups. Stabilizer compositions are provided comprising a phenolic antioxidant and such phosphites as well as synthetic resin compositions having an enhanced resistance to deterioration by heat and/or light due to the presence of such a phosphite and/or stabilizer composition.

  2,6-二叔丁基苯基季戊四醇螺双磷酸盐具有以下结构： 其中 R 是具有 1 至 6 个碳原子的烷基； R 是甲基或乙基 R2 选自具有 1 至约 18 个碳原子的烷基；具有 3 至约 12 个碳原子的环烷基；具有 6 至约 30 个碳原子的烷芳基和芳基；这些基团被 1 至约 4 个氧醚-0-和/或羧酸酯-COO-基团取代；具有 2 至约 18 个碳原子和 2 至约 10 个羟基的多元醇的残余物；以及具有 6 至约 18 个碳原子和 2 至约 10 个酚类羟基的多元酚的残余物。 稳定剂组合物包括酚类抗氧化剂和此类亚磷酸酯以及合成树脂组合物，由于此类亚磷酸酯和/或稳定剂组合物的存在，合成树脂组合物的耐热和/或耐光性得到增强。
• Hindered bis-phenol phenyl phosphites and synthetic resin compositions having enhanced stability to heat and light
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0032681A2

  公开（公告）日：1981-07-29

  Hindered bis-phenol phenyl phosphites are provided having the structure: wherein: R is selected from the group consisting of alkyl having from one up to about eighteen carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; alkaryl and aryl having from six to about eighteen carbon atoms; preferably, a bulky group such as iso, secondary or tertiary alkyl having from three to about ten carbon atoms; or cycloalkyl having six to twelve carbon atoms; R, and R2 are each selected from the group consisting of hydrogen; alkyl having from one to about eighteen carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; alkaryl and aryl having from six to about eighteen carbon atoms; and are preferably in a position ortho to a phenolic hydroxyl or phenoxy group, if available; R3 is alkylene having from one to about six carbon atoms; R4 is selected from the group consisting of alkylene, cycloalkylene, and aralkylene, the residue of a monohydric or polyhydric alcohol, having from one to about eighteen carbon atoms, and from none to three hydroxyl groups (originally one to four hydroxyl groups); Y is selected from the group consisting of a direct carbon to carbon bond; thio sulfur -S-; oxy oxygen -0-; alkylidene having from one to about six carbon atoms; and cycloalkylidene having from four to about eight carbon atoms; and n is 1, 2, 3, or 4, according to the valence of R4; as well as synthetic resin compositions having an enhanced resistance to deterioration by heat and/or light due to the presence of an organic phosphite of this class.

  提供了具有以下结构的受阻双酚苯基磷酸盐： 其中 R 选自具有 1 至约 18 个碳原子的烷基、具有 3 至约 12 个碳原子的环烷基、具有 6 至约 18 个碳原子的芳基和芳烷基组成的组中；最好是具有 3 至约 10 个碳原子的大块基团，如异烷基、仲烷基或叔烷基；或具有 6 至 12 个碳原子的环烷基； R和R2各自选自由氢、具有 1 至约 18 个碳原子的烷基、具有 3 至约 12 个碳原子的环烷基、具有 6 至约 18 个碳原子的烷芳基和芳基组成的组，且最好位于酚羟基或酚氧基的正交位置（如有）； R3 是具有 1 至约 6 个碳原子的亚烷基； R4 选自由烷基、环烷基、芳烷基、一元醇或多元醇的残余物组成的组，具有 1 至约 18 个碳原子，无至 3 个羟基（最初为 1 至 4 个羟基）； Y 选自以下组别：碳-碳直接键；硫-硫-S-；氧-氧-0-；具有一至六个碳原子的亚烷基；以及具有四至八个碳原子的亚环烷基；以及 根据 R4 的化合价，n 为 1、2、3 或 4；以及合成树脂组合物，由于该类有机亚磷酸酯的存在，其耐热和/或耐光性得到增强。
• 2,6-Di-tertiary butyl phenyl phosphites and synthetic resin compositions containing these phosphites
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0033395A2

  公开（公告）日：1981-08-12

  2,6-Di-tertiary butyl phenyl phosphites are provided having the structure: wherein: R is selected from the group consisting of hydrogen, methyl, ethyl, and (CH2)mCOOR, where R is selected from the group consisting of alkyl having from one up to about ten carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; alkaryl and aryl having from six to about twelve carbon atoms; and m is a number within the range from 0 to 5; R2 is selected from the group consisting of hydrogen, alkyl having from one to about twenty-two carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; alkaryl and aryl having from six to about eighteen carbon atoms; the residue of a polyhydric alcohol having from two to about eighteen carbon atoms, and from two to three hydroxyl groups; and the residue of a polyphenol having from six to about eighteeen carbon atoms and from two to about ten phenolic hydroxyl groups; R3 is selected from the group consisting of hydrogen and P(OR2)2; Z is the bivalent or trivalent residue of a polyhydric alcohol having from two to about eighteen carbon atoms, and from two to three hydroxyl groups; or of a polyphenol having from six to about eighteen carbon atoms and from two to about ten phenolic hydroxyl groups; n, is 0 or 1; and n2 is a number from 1 to 5; as well as synthetic resin compositions having an enhanced resistance to deterioration by heat and/or light due to the presence of an organic phosphite of this class.

  2,6-二叔丁基苯基亚磷酸酯具有以下结构： 其中 R选自由氢、甲基、乙基和(CH2)mCOOR组成的组，其中R选自由具有1至约10个碳原子的烷基、具有3至约12个碳原子的环烷基、具有6至约12个碳原子的烷芳基和芳基组成的组，m是0至5范围内的数字； R2 选自由氢、具有 1 至约 22 个碳原子的烷基、具有 3 至约 12 个碳原子的环烷基、具有 6 至约 18 个碳原子的烷芳基和芳基、具有 2 至约 18 个碳原子和 2 至 3 个羟基的多元醇残基、具有 6 至约 8 个碳原子和 2 至约 10 个酚羟基的多元酚残基组成的组； R3 选自氢和 P(OR2)2 组成的组； Z 是二价或三价多元醇的残基，该多元醇具有 2 至约 18 个碳原子和 2 至 3 个羟基；或具有 6 至约 18 个碳原子和 2 至约 10 个酚羟基的多元酚的残基； n 是 0 或 1；以及 n2 是 1 至 5 的数字；以及合成树脂组合物，由于含有该类有机亚磷酸酯，其耐热和/或耐光变质的性能得到增强。
• Compositions containing organic phosphite esters having improved resistance to hydrolysis in the presence of water
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0168721A1

  公开（公告）日：1986-01-22

  Organic phosphite esters having improved hydrolytic stability are provided, comprising an amount of hexamethylene tetramine sufficient to improve resistance to hydrolysis in the presence of water.

  本发明提供了具有更佳水解稳定性的有机亚磷酸酯，其中包含的六亚甲基四胺含量足以提高其在水中的抗水解性。
• Alkylidene bisphenol phosphites and phosphates having 2,2,6,6-tetramethyl piperidinyl groups and synthetic resin compositions
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0149259A2

  公开（公告）日：1985-07-24

  Alkylidene bisphenol phosphites and phosphates having 2,2,6,6-tetramethyl piperidinyl groups are provided having the formula: wherein: R, is alkyl having from one to about twelve carbon atoms; R2, R3 and R4 are each selected from the group consisting of hydrogen and alkyl having from one to about twelve carbon atoms; m is 0 or 1; n is 0 or 1; X is selected from the group consisting of wherein: R5 is selected from the group consisting of hydrogen oxyl O, alkyl having from one to about twelve carbon atoms; aryl alkyl having from seven to about eighteen carbon atoms: 2,3-epoxypropyl, acyl having from one to about eight carbon atoms and in which Rs is selected from the group consisting of hydrogen, alkyl having from one to about twelve carbon atoms and phenyl, and Y, is selected from the group consisting of hydrogen; acyl having from one to about twelve carbon atoms; and Z, is selected from the group consisting of -CH and wherein R7 is alkyl having from one to about twelve carbon atoms: and wherein: R6 is selected from the group consisting of hydrogen, alkyl having from one to about twelve carbon atoms and phenyl; and Z2 is selected from the group consisting of >C=O; -CH-O-Y2; in which R7 is alkyl having from one to about twelve carbon atoms; R8 is alkylene having from one to about eight carbon atoms and Y2 is selected from the group consisting of hydrogen and acyl having from one to about eight carbon atoms.

  提供了具有 2，2，6，6-四甲基哌啶基团的亚烷基双酚亚磷酸酯和磷酸酯，其结构式为 其中 R是具有1至约12个碳原子的烷基； R2、R3 和 R4 分别选自由一个至约十二个碳原子的氢和烷基组成的组； m为0或1 n 为 0 或 1； X 选自以下组成的组 其中 R5 选自由氢氧 O、具有 1 至约 12 个碳原子的烷基、具有 7 至约 18 个碳原子的芳基烷基组成的组：2,3-环氧丙基，具有 1 至 8 个碳原子的酰基，以及 其中 Rs 选自氢、具有 1 至约 12 个碳原子的烷基和苯基组成的组，Y 选自氢、具有 1 至约 12 个碳原子的酰基组成的组，以及 Z，选自由-CH 和-CH烷基组成的组。 其中 R7 是具有 1 至约 12 个碳原子的烷基：和 其中 R6 选自由氢、具有 1 至 12 个碳原子的烷基和苯基组成的组；以及 Z2 选自由 >C=O；-CH-O-Y2 组成的组； 其中 R7 是具有 1 至约 12 个碳原子的烷基；R8 是具有 1 至约 8 个碳原子的亚烷基；Y2 选自氢和具有 1 至约 8 个碳原子的酰基组成的组。