bis(2-aminopyridine-κN(1))(benzoato-κO)silver(I) | 604813-10-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(2-aminopyridine-κN(1))(benzoato-κO)silver(I)
• 英文别名: [benzoatodi(2-amino-pyridine)silver(I)]；Bis(2-aminopyridine-kappaN^1^)(benzoato-kappaO)silver(I)；silver;pyridin-2-amine;benzoate
• CAS: 604813-10-7
• 化学式: C₁₇H₁₇AgN₄O₂
• 分子量: 417.216
• InChiKey: PKAPOBCGJQGKDA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.38
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  118
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2-氨基吡啶 、 苯甲酸 、 silver(l) oxide 在 NaOH 作用下， 以 氨 为溶剂， 以22%的产率得到bis(2-aminopyridine-κN(1))(benzoato-κO)silver(I)
  参考文献：
  名称：

  Synthesis and Characterization of Ag(I) Salts with Pyridine Derivatives

  摘要：

  Four silver( I) complexes with three pyridyl ligands, 3-amino-pyridine (L-1), 2-amino-pyridine (L-2), and 4,4'-bipyridine (L-3) were synthesized and determined by single-crystal X-ray diffraction. The silver( I) ions in the complexes [Ag(L-1)(2)](CF3SO3) ( 1) and [Ag(L-1)(2)] HCO3 center dot 4H(2)O ( 2) adopt a linear geometry and those in [Ag(L-2)(2)(C6H5COO)] ( 3) takes a Y-shape. [Ag(L-3)(CH3COOH)] (n)(NO3)(n) center dot 10H(2)O ( 4) is a polymeric silver( I) complex which consists of four parallel, one-dimensional chains, where there exist two crystallographically different kinds of Ag( I) cations, one is coordinated in a T-shape fashion and the other in a slightly distorted linear geometry.

  DOI：

  10.1081/sim-200035691

文献信息

• Bis(2-aminopyridine-κ<i>N</i>¹)(benzoato-κ<i>O</i>)silver(I)
  作者：Hai-Liang Zhu、Anwar Usman、Hoong-Kun Fun、Xian-Jiang Wang

  DOI：10.1107/s0108270103008916

  日期：2003.6.15

  In the title compound, [Ag(C7H5O2)(C5H6N2)(2)], the Ag-I atom is tricoordinated by two independent pyridine N atoms and one benzoate O atom in a nearly planar geometry. An intramolecular N-H...O hydrogen bond forms an S(8) graph ring. The packing is built from molecular layers stabilized by two types of N-H...O hydrogen bond. Intermolecular Ag...N and intramolecular Ag...O contacts were also observed, together with three weak intermolecular C-H...pi interactions.