bis(2,5-dimethyl-4-chlorophenyl)sulfone | 92969-34-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(2,5-dimethyl-4-chlorophenyl)sulfone
• 英文别名: 1-Chloro-4-(4-chloro-2,5-dimethylphenyl)sulfonyl-2,5-dimethylbenzene
• CAS: 92969-34-1
• 化学式: C₁₆H₁₆Cl₂O₂S
• 分子量: 343.274
• InChiKey: WESJZFLINNRYDJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Poly(Arylene sulfide sulfone) polymer containing ether groups
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0336145A1

  公开（公告）日：1989-10-11

  A two-step process to make a poly(arylene sulfide sulfone) polymer exhibiting improved high temperature properties is described. In the first step a prepolymer characterized as dihalo-terminated polyethersulfone oligomers is prepared by reacting an aromatic diphenol with an excess of a dihalo aromatic sulfone. In the second step the excess dihalo aromatic sulfone and the oligomers are copolymerized in the presence of a sulfur source to form a poly(arylene sulfide sulfone) polymer. An alkali metal carboxylate is present in the second step. The polymers exhibit improved softening temperature and glass transition temperature and are useful in high temperature applications.

  本文介绍了一种分两步制备聚（芳烯烃砜）聚合物的工艺，该聚合物具有更好的高温特性。在第一步中，通过芳香族二酚与过量的二卤代芳香族砜反应，制备出以二卤代端聚醚砜低聚物为特征的预聚物。在第二步中，过量的二卤代芳香族砜和低聚物在硫源存在下共聚形成聚芳基砜聚合物。碱金属羧酸盐存在于第二步中。这种聚合物的软化温度和玻璃化温度都有所提高，适用于高温应用。
• Method for the manufacture of poly(aryl ethers) using at least one organic base
  申请人：SOLVAY SPECIALTY POLYMERS USA, LLC

  公开号：US10745522B2

  公开（公告）日：2020-08-18

  The present invention relates to a method for the manufacture of a poly(aryl ether) such as a poly(aryl ethersulfone) or a poly(aryl ether ketone) including the use of an organic base having a pKa of at least 10.

  本发明涉及一种制造聚（芳基醚），如聚（芳基醚砜）或聚（芳基醚酮）的方法，包括使用 pKa 至少为 10 的有机碱。
• METHOD FOR THE MANUFACTURE OF POLY(ARYL ETHERS) USING AT LEAST ONE ORGANIC BASE
  申请人：Solvay Specialty Polymers USA, L.L.C.

  公开号：EP3209708A1

  公开（公告）日：2017-08-30
• US4808694A
  申请人：——

  公开号：US4808694A

  公开（公告）日：1989-02-28
• US5045367A
  申请人：——

  公开号：US5045367A

  公开（公告）日：1991-09-03