| 861819-49-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 861819-49-0
• 化学式: C₂₈H₂₄NO₂PPd
• 分子量: 543.898
• InChiKey: VOCGUDFYQGBMBB-CHBAEZQBSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  chloromethyl(1,5-cyclooctadiene)palladium(II) 、 2,6-二甲酰-4-甲基苯酚 、 2-(二苯基膦)苯胺 在 Et₃N 作用下， 以 甲醇 为溶剂， 以13%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of nickel and palladium complexes containing hetero-multidentate PNO ligands

  摘要：

  Formation of mono- and dinuclear complexes containing ligands stemmed from the condensation of 2,6-diformyl-4-methylphenol derivatives with 2-(diphenylphosphino)aniline (P similar to N) was investigated. Condensation of P similar to N with 2,6-diformyl-4-methylanisole yielded the desired bis(imine-phosphine) L-3, but provided the cyclized benzoazaphospholium compound with 2,6-diformyl-4methylphenol. Complexation of L-3 with (COD)PdCl2 gave the dinuclear complex 4. On the other hand, L-3 underwent the intramolecular cyclization in the presence of (DME)NiCl2 via the formation of benzoazaphospholium rings. Template condensation of 2,6-diformyl-4-methylphenol with P similar to N in the presence of metal ions yielded the mononuclear nickel(II) and palladium(II) complexes, respectively. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.03.034