(9-fluorenone)pentachlorotungsten | 138533-82-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: (9-fluorenone)pentachlorotungsten
• CAS: 138533-82-1
• 化学式: C₁₃H₈Cl₅OW
• 分子量: 541.321
• InChiKey: KLMWFNRLXHQWJB-UHFFFAOYSA-I

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  9-芴酮 、 (diethyl ether)pentachlorotungsten 以 二氯甲烷 为溶剂， 生成 (9-fluorenone)pentachlorotungsten
  参考文献：
  名称：

  Reduction of WCl6 by allyltrimethylsilane. A convenient method to prepare WCl5(OEt2) and some other derivatives of WCl5

  摘要：

  WCl6 was reacted with excess allyltrimethylsilane in diethyl ether solution at low temperature. The main product in the reaction was shown to be WCl5(OEt2) which was isolated as black-green air- and moisture-sensitive crystals. WCl5(OEt2) was reacted with different Lewis bases, e.g. pyridine and 9-fluorenone to yield the new compounds WCl5 (pyridine) and WCl5(9-fluorenone). The latter most likely being an oxygen bonded complex.

  DOI：

  10.1016/s0277-5387(00)86127-6