tris[2-(dimethylamino)phenyl]methoxygermane | 198204-40-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tris[2-(dimethylamino)phenyl]methoxygermane
• 英文别名: 2-[bis[2-(dimethylamino)phenyl]-methoxygermyl]-N,N-dimethylaniline
• CAS: 198204-40-9
• 化学式: C₂₅H₃₃GeN₃O
• 分子量: 464.147
• InChiKey: PMXOLMMILUGAIA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  30.0
• 可旋转键数：
  7.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  18.95
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  tris[2-(dimethylamino)phenyl]methoxygermane 在 silica gel 、 air 作用下， 以 正己烷 、 乙酸乙酯 为溶剂， 生成 tris[2-(dimethylamino)phenyl]germanol
  参考文献：
  名称：

  Synthesis and Structures of Tris[2-(dimethylamino)phenyl]silane and -germane Compounds

  摘要：

  Tris[2-(dimethylamino)phenyl]silane and -germane compounds (1 and 2) were synthesized and characterized by X-ray crystallography. Three 2-(dimethylamino)phenyl groups in the hydrosilane (1a) and hydrogermane (1b) encapsulate the hydrogen atom bonded to silicon and germanium, which results in the short Si-H and Ge-H bonds and an increase in the s character of the bonds. The silanol (2a) and germanol (2b) exist as monomers through the intramolecular hydrogen bonding between the hydroxy group and one of the amino groups.

  DOI：

  10.1021/om970548n
• 作为产物：
  描述：

  2-溴-N,N-二甲基苯胺 、 甲氧基锗 在 n-butyllithium 作用下， 以 四氢呋喃 、 乙醚 、 正己烷 为溶剂， 生成 tris[2-(dimethylamino)phenyl]methoxygermane
  参考文献：
  名称：

  Synthesis and Structures of Tris[2-(dimethylamino)phenyl]silane and -germane Compounds

  摘要：

  Tris[2-(dimethylamino)phenyl]silane and -germane compounds (1 and 2) were synthesized and characterized by X-ray crystallography. Three 2-(dimethylamino)phenyl groups in the hydrosilane (1a) and hydrogermane (1b) encapsulate the hydrogen atom bonded to silicon and germanium, which results in the short Si-H and Ge-H bonds and an increase in the s character of the bonds. The silanol (2a) and germanol (2b) exist as monomers through the intramolecular hydrogen bonding between the hydroxy group and one of the amino groups.

  DOI：

  10.1021/om970548n