| 864234-69-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 864234-69-5
• 化学式: C₂₄H₁₈CoN₂O₄
• 分子量: 457.411
• InChiKey: OJORCLBQQFYZKI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  oxovanadium(IV) sulfate 、 、 邻苯二胺 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of hetero binuclear macrocyclic CoV complex bonded to chemically modified alumina support for oxidation of cyclohexane using oxygen

  摘要：

  A binuclear complex (MAMBL2+)-M-II-L-IV [with M-A(II)=Co-II and M-B(IV) =V-IV] has been synthesized with a macrocyclic ligand prepared by condensing 2 equiv. of 2,6-difonnyl-4-methylphenol with 2 equiv. of 1,2-phenylenediamine. This has been immobilized on a carbamate-modified alumina support by covalently binding it to the surface. The TGA analysis of the final catalyst showed that it is thermally stable up to 251 degrees C and it has been shown that it serves as a catalyst for oxidation of cyclohexane, forming cyclohexanone and cyclohexanol in the ratio of 14:1 as identified by the GC/MS analysis. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2004.11.022
• 作为产物：
  描述：

  2,6-二甲酰-4-甲基苯酚 、 cobalt(II) acetate 、 邻苯二胺 以 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of hetero binuclear macrocyclic CoV complex bonded to chemically modified alumina support for oxidation of cyclohexane using oxygen

  摘要：

  A binuclear complex (MAMBL2+)-M-II-L-IV [with M-A(II)=Co-II and M-B(IV) =V-IV] has been synthesized with a macrocyclic ligand prepared by condensing 2 equiv. of 2,6-difonnyl-4-methylphenol with 2 equiv. of 1,2-phenylenediamine. This has been immobilized on a carbamate-modified alumina support by covalently binding it to the surface. The TGA analysis of the final catalyst showed that it is thermally stable up to 251 degrees C and it has been shown that it serves as a catalyst for oxidation of cyclohexane, forming cyclohexanone and cyclohexanol in the ratio of 14:1 as identified by the GC/MS analysis. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2004.11.022