1,1,1-trifluoro-hex-2-ene | 53392-87-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: 1,1,1-trifluoro-hex-2-ene
• 英文别名: 1,1,1-trifluorohex-2-ene
• CAS: 53392-87-3
• 化学式: C₆H₉F₃
• 分子量: 138.133
• InChiKey: RDOOLLOGNZMZOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  戊烯 、 三氟乙酸 在 sodium hydroxide 作用下， 以 水 、 乙腈 为溶剂， 生成 1,1,1-trifluorohexane 、 1,1,1-trifluorohex-3-ene 、 1,1,1-trifluoro-hex-2-ene 、 4,5-bis-(2,2,2-trifluoro-ethyl)-octane
  参考文献：
  名称：

  烯烃双键与电化学生成的多氟烷基的反应

  摘要：

  将电化学产生的多氟烷基自由基加成到烯烃双键上，说明了获得许多新颖的多氟烷基衍生物的新方法。

  DOI：

  10.1039/c39740000323

文献信息

• MANUFACTURE OF FLUORINATED ALCOHOLS
  申请人：Der Puy Van Michael

  公开号：US20050256331A1

  公开（公告）日：2005-11-17

  Present invention relates to a process for the manufacture of fluorinated alcohols as well as borates which are employed in the manufacture of the fluorinated alcohols. Fluorinated alcohols of the formulae HOCHRCF(CF 3 )CHFCF(CF 3 ) 2 and HOCHRCF(CF(CF 3 ) 2 )CHFCF 3 , HOCHRCF(CF 2 CF 3 )CH(CF 3 ) 2 and HOCHRC(CF 3 ) 2 CHFCF 2 CF 3 are made by heating a mixture of a borate of the formula (RCH 2 O) 3 B, wherein R═H or a C 1 to C 7 alkyl group, with perfluoro-4-methyl-2-pentene or perfluoro-2-methyl-2-pentene and a free-radical initiator to form a mixture of borates, optionally separating the mixture of borates from any reactants, solvents, and by-products; hydrolyzing the mixture of borates to form a hydrolysis product mixture; and separating the alcohols from the hydrolysis product mixture.

  本发明涉及一种用于制造氟化醇和硼酸盐的工艺，该硼酸盐用于制造氟化醇。通过加热公式为HOCHRCF(CF3)CHFCF(CF3)2和HOCHRCF(CF(CF3)2)CHFCF3、HOCHRCF(CF2CF3)CH(CF3)2和HOCHRC(CF3)2CHFCF2CF3的氟化醇的混合物与公式为(RCH2O)3B的硼酸盐（其中R=H或C1至C7烷基）以及全氟-4-甲基-2-戊烯或全氟-2-甲基-2-戊烯和自由基引发剂反应，形成硼酸盐的混合物，可选择地将硼酸盐的混合物与任何反应物、溶剂和副产物分离；水解硼酸盐的混合物以形成水解产物混合物；并从水解产物混合物中分离出醇。
• METHODS FOR MAKING FOAMS USING BLOWING AGENTS COMPRISING UNSATURATED FLUOROCARBONS
  申请人：E I DU PONT DE NEMOURS AND COMPANY

  公开号：US20150080485A1

  公开（公告）日：2015-03-19

  Disclosed herein are blowing agents comprising fluorocarbons and/or hydrofluorocarbons useful in foamable compositions. Also disclosed are methods for forming a foam comprising the aforementioned blowing agents.

  本文揭示了含有氟碳化合物和/或氢氟碳化合物的发泡剂，可用于泡沫组合物中。还揭示了用于形成含有上述发泡剂的泡沫的方法。
• Micropatterning of plasma polymerized coatings
  申请人：Scandinavian Micro Biodevices

  公开号：EP1260863A1

  公开（公告）日：2002-11-27

  This invention relates to a lift-off process for micro-patterning of plasma-polymerised coatings using micro lithography. The plasma-polymerised surface may be hydrophobic, hydrophilic, cell non-adhesive surface (i.e. a surface which prevents bio-fouling), cell-adhesive surface (surface with high adhesion to cells thereby promoting cell-attachment), conducting, acidic, alkaline, etc. The invention enables patterning of a single or multiple plasma polymerised surfaces on the same substrate. The invention also relates to substrates and devices for use in cell sorting or cell-capture procedures.

  本发明涉及一种利用微光刻技术对等离子聚合涂层进行微图案化的升华工艺。等离子聚合表面可以是疏水性表面、亲水性表面、细胞非粘附性表面（即防止生物污染的表面）、细胞粘附性表面（对细胞具有高粘附性从而促进细胞附着的表面）、导电性表面、酸性表面、碱性表面等。本发明可在同一基底上对单个或多个等离子聚合表面进行图案化。本发明还涉及用于细胞分选或细胞捕获程序的基底和装置。
• Method for the preparation of a substrate for immobilising chemical compounds and the substrate and the use thereof
  申请人：——

  公开号：US20040086660A1

  公开（公告）日：2004-05-06

  The invention relates to a method of providing a solid substrate for immobilizing chemical compounds particular biomolecules. The method comprises the steps of providing a basis substrate, and treating the surface of the basis substrate with a monomer gas in a plasma generated by a power source selected from the group consisting of multiple phase AC supply and multiple DC supply, wherein the intensity of said plasma being at the most 5.0 W/I, such as at the most 3.0 W/I, and said monomer gas comprising one or more types of monomers which is plasma polymerized onto the surface to thereby provide the surface of the solid substrate with chemically reactive groups. The invention also relates to a substrate obtainable by the method, and a process for immobilizing a chemical compound to a surface of such solid substrate. The method is relatively simple and economically feasibly, and the substrate has a high quality and a high concentration of functionalities.

  本发明涉及一种提供固定化合物特别是生物大分子的固体基底的方法。该方法包括以下步骤：提供基底，在由选自多相交流电源和多相直流电源的一组电源产生的等离子体中用单体气体处理基底的表面，其中所述等离子体的强度不超过 5.0 W/I，例如不超过 3.0 W/I，所述单体气体包括一种或多种类型的单体，这些单体通过等离子体聚合到表面，从而使固体基底的表面具有化学反应基团。本发明还涉及一种可通过该方法获得的基底，以及一种将化合物固定到这种固体基底表面的工艺。该方法相对简单且经济可行，基底具有高质量和高浓度的功能性。
• Method of plasma polymerisation of substituted benzenes, polymeric material obtainable by the method, and use thereof
  申请人：——

  公开号：US20040202880A1

  公开（公告）日：2004-10-14

  A method of plasma polymerisation of monomers for providing a cross-linked polymeric material, the method comprising: treating a monomer gas in a plasma, said monomer gas comprising one or more monomers selected from substituted benzenes, wherein said plasma is generated by a multiple phase AC supply or a DC supply at a plasma power density allowing a substantial portion of substituent groups of said substituted benzenes to be preserved.

  一种用于提供交联聚合物材料的单体等离子聚合方法，该方法包括：在等离子体中处理单体气体，所述单体气体包括一种或多种选自取代苯的单体，其中所述等离子体由多相交流电源或直流电源产生，等离子体功率密度允许保留所述取代苯的大部分取代基。