Disclosed are adhesive compositions which are solid but spreadable to form a coating on substrates. Solutions of the adhesive composition are formed into a gel in a useful form such as a stick. The adhesive composition comprises dibenzal sorbitol gelling agent and polyesters derived from components (A), (B) and (C) as follows:
(A) at least one dicarboxylic acid,
(B) at least one diol, at least 20 mole percent of the diol component being a poly(ethylene glycol) having the formula H(OCH2-CH2)n-OH wherein n is an integer of from 2 to about 10, and
(C) at least one difunctional dicarboxylic acid sulfomonomer containing a -SO3M group attached ao an aromatic nucleus, wherein M is hydrogen or Na+, Li+, K+, or a combination thereof, the sulfomonomer component constituting at least about 8 mole percent to about 45 mole percent of the sum of the moles of said components (A) and (C).
所公开的粘合剂组合物为固体,但可涂抹在基材上形成涂层。该粘合剂组合物的溶液以有用的形式(如棍棒)形成凝胶。该粘合剂组合物包括
二苯甲醇山梨醇胶凝剂和由以下组分(A)、(B)和(C)衍生的聚酯:
(A) 至少一种二
羧酸、
(B) 至少一种二元醇,其中至少 20 摩尔%的二元醇成分为聚
乙二醇,其式为 H(O -
CH2)n-OH 其中 n 为 2 至约 10 的整数,以及
(C) 至少一种双官能团二
羧酸磺酰基单体,该磺酰基单体含有连接芳香核的 -SO3M 基团,其中 M 为氢或 Na+、Li+、K+ 或它们的组合,磺酰基单体组分占所述组分(A)和(C)摩尔数总和的至少约 8 摩尔%至约 45 摩尔%。