[Ni(diethyl 5,6,7,8,15,16-hexahydro-6,7-dioxodibenzo[1,4,8,11]-tetraazacyclotetradecine-13,18-dicarboxylate] | 69198-63-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: [Ni(diethyl 5,6,7,8,15,16-hexahydro-6,7-dioxodibenzo[1,4,8,11]-tetraazacyclotetradecine-13,18-dicarboxylate]
• 英文别名: diethyl 3,4-dioxo-13,16-diaza-2,5-diazanidatricyclo[16.4.0.06,11]docosa-1(22),6,8,10,12,16,18,20-octaene-12,17-dicarboxylate;nickel(2+)
• CAS: 69198-63-6
• 化学式: C₂₄H₂₂N₄NiO₆
• 分子量: 521.152
• InChiKey: MRKDVHOTFUFYSU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  甲醇 、 copper(II) perchlorate hexahydrate 、 [Ni(diethyl 5,6,7,8,15,16-hexahydro-6,7-dioxodibenzo[1,4,8,11]-tetraazacyclotetradecine-13,18-dicarboxylate] 以 甲醇 为溶剂， 以49%的产率得到[Cu(Ni(diethyl 5,6,7,8,15,16-hexahydro-6,7-dioxodibenzo[1,4,8,11]-tetraazacyclotetradecine-13,18-dicarboxylate)2(CH3OH)2][ClO4]2
  参考文献：
  名称：

  Synthesis and supramolecular structure of a macrocyclic NiIICuIINiII trinuclear complex [CuII(NiIIL)2(CH3OH)2](ClO4)2

  摘要：

  A new (NiCuNiII)-Cu-II-Ni-II trinuclear complex [Cu-II((NiL)-L-II)(2)((CHOH)-O-3)(2)](ClO4)(2) has been synthesized by self-assembly and characterized by X-ray crystallography. L is the dianion of diethyl 5,6,7,8,15,16-hexahydro-6,7-dioxodibenzo-[1,4,8,11]-tetraazacyclotetradecine-13,18-dicarboxylate. The coordination geometnes around two Ni-II ions are completely same and distorted N-4-square planes. Cu-II, ion resides in a distorted octahedral 06 coordination environment. In the crystal, a new kind of strong supramolecular interaction is observed and results in 1D supramolecular chains of trinuclear cations. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(02)00407-6