1,2-benzylidenedioxy-7-(2-hydroxybenzylideneamino)-4-azaheptane | 503415-88-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 1,2-benzylidenedioxy-7-(2-hydroxybenzylideneamino)-4-azaheptane
• CAS: 503415-88-1
• 化学式: C₂₀H₂₄N₂O₃
• 分子量: 340.422
• InChiKey: MRRCXVRDBOHAPD-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  copper(II) choride dihydrate 、 1,2-benzylidenedioxy-7-(2-hydroxybenzylideneamino)-4-azaheptane 以 乙醇 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  摘要：

  1,2-Benzylidenedioxy-7-(2-hydroxybenzylideneamino)-4-azaheptane was synthesized by reaction of 1,2-benzylidenedioxy-3-chloropropane with 1,3-diaminopropane and subsequent condensation of 1,2-benzylidenedioxy-7-amino-4-azaheptane with salicylaldehyde. Complexes of 1,2-benzylidenedioxy-7-(2-hydroxybenzylideneamino)-4-azaheptane with cobalt(II), nickel(II), and copper(II) salts were obtained. The structure of the ligand and its complexes was established on the basis of their elemental compositions, IR, UV, and H-1 NMR spectra, magnetic susceptibilities, and thermogravimetric data.

  DOI：

  10.1023/a:1020844216503
• 作为产物：
  描述：

  邻甲基苄醇 、 7-amino-1,2-benzylidenedioxy-4-azaheptane 在 溶剂黄146 作用下， 以 乙醇 为溶剂， 反应 24.0h， 以68%的产率得到1,2-benzylidenedioxy-7-(2-hydroxybenzylideneamino)-4-azaheptane
  参考文献：
  名称：

  摘要：

  1,2-Benzylidenedioxy-7-(2-hydroxybenzylideneamino)-4-azaheptane was synthesized by reaction of 1,2-benzylidenedioxy-3-chloropropane with 1,3-diaminopropane and subsequent condensation of 1,2-benzylidenedioxy-7-amino-4-azaheptane with salicylaldehyde. Complexes of 1,2-benzylidenedioxy-7-(2-hydroxybenzylideneamino)-4-azaheptane with cobalt(II), nickel(II), and copper(II) salts were obtained. The structure of the ligand and its complexes was established on the basis of their elemental compositions, IR, UV, and H-1 NMR spectra, magnetic susceptibilities, and thermogravimetric data.

  DOI：

  10.1023/a:1020844216503