sec-Butyl-thiophosphoramidic acid O-methyl ester O'-(5-methyl-2-nitro-phenyl) ester | 36335-66-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: sec-Butyl-thiophosphoramidic acid O-methyl ester O'-(5-methyl-2-nitro-phenyl) ester
• 英文别名: N-[methoxy-(5-methyl-2-nitrophenoxy)phosphinothioyl]butan-2-amine
• CAS: 36335-66-7
• 化学式: C₁₂H₁₉N₂O₄PS
• 分子量: 318.334
• InChiKey: NZZKZYVLBLDMDG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  108
• 氢给体数：
  1
• 氢受体数：
  6

文献信息

• N'-Phenyl-N-methylurea derivatives, processes for their preparation and their uses as herbicides
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0017706A2

  公开（公告）日：1980-10-29

  Novel N'-phenyl-N-methylurea derivatives of the formula: wherein R is a C4-C10 cycloalkyl group, a C4-C10 cycloalkenyl group, a C4-C10 cycloalkyl group condensed with a benzene ring or substituted with at least one C1-C4 alkyl group or a C4-C,o cycloalkenyl group condensed with a benzene ring or substituted with a C1-C4 alkyl group, Z is a C1-C4 alkylene group which may have an atom of oxygen and/or sulfur at the terminal of and/or inside the carbon chain, Y is an oxygen atom or a sulfur atom, A is a hydrogen atom, a methyl group or a methoxy group and n is an integer of 0 or 1 with the profiso that in the chain consisting of -(Z)n-Y-, oxygen and/or sulfur atoms can not be present in succession, are described, which show pronounced herbicidal activity against a wide variety of weeds in the cultivation of crop plants without any material toxicity to mammals and any chemical injury to said crop plants. The preparation of the compounds and intermediates therefor and the herbicidal activity of the compounds are described and exemplified.

  式中的新型 N'-苯基-N-甲基脲衍生物： 其中 R 是 C4-C10 环烷基、C4-C10 环烯基、与苯环缩合或被至少一个 C1-C4 烷基取代的 C4-C10 环烷基或与苯环缩合或被 C1-C4 烷基取代的 C4-C,o 环烯基，Z 是 C1-C4 亚烷基，该亚烷基可在碳链的末端和/或碳链的内部具有氧原子和/或硫原子，Y 是氧原子或硫原子、A 是氢原子、甲基或甲氧基，n 是 0 或 1 的整数，但在由 -(Z)n-Y- 组成的链中，氧原子和/或硫原子不能连续存在。本文还描述并举例说明了这些化合物及其中间体的制备方法和除草活性。
• N-(2-(cyclopropyl)ethoxy)phenylanilide derivatives, their production, herbicidal compositions and their use, N-(2-(cyclopropyl)ethoxy)-aniline compounds and N-(2-(cyclopropyl)ethoxy)nitrobenzene compounds
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0037106A2

  公开（公告）日：1981-10-07

  N-[2-(cyclopropyl)ethoxy]phenylanilide derivatives of the formula I wherein R,, R2 and R3, which may be same or different, are each hydrogen or C1-C4 alkyl, X is chlorine or bromine, Y is hydrogen, chlorine, bromine, fluorine or iodine and Z is N,N-dimethylamino, N-methoxy-N-methylamino, C1-C4 alkyl or C3-C6 cycloalkyl, and intermediates for their preparation are provided. The compounds of the formula I are useful as herbicides.

  式 I 的 N-[2-(环丙基)乙氧基]苯基苯胺衍生物 其中 R、R2 和 R3（可以相同或不同）各自为氢或 C1-C4 烷基，X 为氯或溴，Y 为氢、氯、溴、氟或碘，Z 为 N,N-二甲基氨基、N-甲氧基-N-甲基氨基、C1-C4 烷基或 C3-C6 环烷基，并提供了用于制备它们的中间体。式 I 的化合物可用作除草剂。
• US4315768A
  申请人：——

  公开号：US4315768A

  公开（公告）日：1982-02-16
• US4381935A
  申请人：——

  公开号：US4381935A

  公开（公告）日：1983-05-03
• US4378992A
  申请人：——

  公开号：US4378992A

  公开（公告）日：1983-04-05