[(μ-S,S-(N,N'-ethylenebis(2-thioacetamidate))nickelate(II))(1,3-bis(diphenylphosphanyl)propane)nickel(II)] | 857352-66-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [(μ-S,S-(N,N'-ethylenebis(2-thioacetamidate))nickelate(II))(1,3-bis(diphenylphosphanyl)propane)nickel(II)]
• 英文别名: [Ni(ema)(μ-S,S')Ni(dppp)]；[Ni(N,N'-ethylenebis(2-mercaptoacetamide(4-)))(μ-S,S')(Ni(1,2-bis(diphenylphosphino)propane)]
• CAS: 857352-66-0
• 化学式: C₃₃H₃₄N₂Ni₂O₂P₂S₂
• 分子量: 734.105
• InChiKey: RSNJTLILHBQCMA-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,3-bis[(diphenylphosphino)propane]dichloronickel(II) 、 di(tetraethylammonium) (N,N'-ethylenebis(2-thioacetamidate))nickelate(II) 以 乙腈 为溶剂， 以64%的产率得到[(μ-S,S-(N,N'-ethylenebis(2-thioacetamidate))nickelate(II))(1,3-bis(diphenylphosphanyl)propane)nickel(II)]
  参考文献：
  名称：

  Homonuclear dinickel complexes: structural mimics for the dinickel subsite of the A-cluster of acetyl-CoA synthase

  摘要：

  [Ni(ema)(p-S,S')Ni(dppp)] (1) and [Ni(ema)(mu-S,S')Ni(dppe)] (2) have been prepared as synthetic structural analogues of the Ni-Ni subsite of the A-cluster of the enzyme acetyl-CoA synthase by reaction of [Ni(ema)](2-), H(4)ema is N,N'-ethylenebis(2-mercaptoacetamide), with [NiCl2(diphos)], diphos is 1,2-bis(diphenylphosphino)propane (dppp) or 1,2-bis(diphenylphosphino)ethane (dppe). A similar reaction with 1,2-bis(diethylphosphino)ethane did not give the dinuclear product but the trinuclear complex [NEt4](2)[Ni {Ni(ema)(mu-S,S')}(2)] (3). Complexes 1 and 3 have been crystallographically characterised. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.11.026