| 207615-56-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 207615-56-3
• 化学式: C₂₂H₃₀CrF₂I₂N₂
• 分子量: 678.2
• InChiKey: RUSRSKVKIZKPJR-DOHUMTFGSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Li(2,3:5,6-dibenzo-7-azabicyclo[3.2.1]hepta-2,5-diene(1-))*Et2O 、 以 乙醚 为溶剂， 以36%的产率得到
  参考文献：
  名称：

  Deprotonated 2,3:5,6-Dibenzo-7- aza bicyclo[2.2.1]hepta-2,5-diene as a Nitrido Nitrogen Source by Anthracene Elimination: Synthesis of an Iodide(nitride)chromium(VI) Complex

  摘要：

  Instead of azides, which can be explosive and poorly soluble in nonpolar solvents, azabicycloheptadienes can be used to synthesize nitrides. The reaction of diiodide 1 with the lithium amide 3 provides the red nitride 2 in 60 % yield with loss of lithium iodide and anthracene. The remaining iodo ligand in 2 can undergo an exchange reaction with lithium amide 3, but no more anthracene is released.

  DOI：

  10.1002/(sici)1521-3773(19980420)37:7<945::aid-anie945>3.0.co;2-x
• 作为产物：
  描述：

  Chromium(3+);(2-fluoro-5-methylphenyl)-(1,1,1,3,3,3-hexadeuterio-2-methylpropan-2-yl)azanide 、 碘 以 苯 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  Deprotonated 2,3:5,6-Dibenzo-7- aza bicyclo[2.2.1]hepta-2,5-diene as a Nitrido Nitrogen Source by Anthracene Elimination: Synthesis of an Iodide(nitride)chromium(VI) Complex

  摘要：

  Instead of azides, which can be explosive and poorly soluble in nonpolar solvents, azabicycloheptadienes can be used to synthesize nitrides. The reaction of diiodide 1 with the lithium amide 3 provides the red nitride 2 in 60 % yield with loss of lithium iodide and anthracene. The remaining iodo ligand in 2 can undergo an exchange reaction with lithium amide 3, but no more anthracene is released.

  DOI：

  10.1002/(sici)1521-3773(19980420)37:7<945::aid-anie945>3.0.co;2-x