(Cu(HO-2-C6H4CH=NC6H4-2'-SMe)(bpy))(ClO4) | 414859-39-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (Cu(HO-2-C6H4CH=NC6H4-2'-SMe)(bpy))(ClO4)
• 英文别名: (Cu(HO-2-C6H4CH=NC6H4-2'-SMe)(2,2'-bipyridine))(ClO4)
• CAS: 414859-39-5
• 化学式: C₂₄H₂₁CuN₃OS*ClO₄
• 分子量: 562.513
• InChiKey: OXIHHUGLEOOOPH-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  (Cu(O-2-C6H4CH=NC6H4-2'-SMe)(2,2'-bipyridine))(ClO4) 在 ascorbic acid 作用下， 以 水 、 乙腈 为溶剂， 以60%的产率得到(Cu(HO-2-C6H4CH=NC6H4-2'-SMe)(bpy))(ClO4)
  参考文献：
  名称：

  多巴胺β-羟化酶的Cu（B）位点的结构模型：铜（II）配合物的晶体结构，显示了N（3）OS与轴向硫连接的配位。

  摘要：

  A copper(II) complex containing a NSO-donor Schiff base and NN-donor 2,2'-bipyridine has been prepared and structurally characterized. The square pyramidal complex with an axial sulfur ligation is a structural model for the CUB site of dopamine-hydroxylase in its oxidized form. The copper(II) complex is catalytically active in the oxidation of ascorbic acid by dioxygen mediated by a copper(I) species which is proposed to have a four-coordinate structure with a N3S coordination geometry.[GRAPHICS]

  DOI：

  10.1021/ic010926n