(5,10,15,20-tetramesitylporphyrinato)(3-phenylpropyl)rhodium(III) | 1234321-55-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (5,10,15,20-tetramesitylporphyrinato)(3-phenylpropyl)rhodium(III)
• 英文别名: Rh((CH2)3Ph)(tmp)
• CAS: 1234321-55-1
• 化学式: C₆₅H₆₃N₄Rh
• 分子量: 1003.15
• InChiKey: YLFQZQJOEUZBMH-WSJWEZPUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide 在 NaBH₄ 、 NaOH 作用下， 以 ethanol 、 aq. NaOH 为溶剂， 以79%的产率得到(5,10,15,20-tetramesitylporphyrinato)(3-phenylpropyl)rhodium(III)
  参考文献：
  名称：

  Ligand-Enhanced Aliphatic Carbon−Carbon Bond Activation of Nitroxides by Rhodium(II) Porphyrin

  摘要：

  Rh(tmp) underwent Ph3P-enhanced aliphatic carbon carbon bond activation with various nitroxides. (Ph3P)Rh(tmp), rapidly formed from Rh(tmp) and Ph3P, enhanced the rate, selectivity, and yield in comparison to Rh(tmp). From kinetic studies, the rate of reaction showed a first-order dependence on both Rh(tmp) and TEMPO (TEMPO = 2,2,6,6-tetramethylpiperidine-1-oxyl) and saturation kinetics on Ph3P. The rate enhancement of (Ph3P)Rh(tmp) over Rh(tmp) was estimated to be about 11 at 70 degrees C.

  DOI：

  10.1021/om1000869

文献信息

• Regioselective and Room-Temperature Carbon–Carbon Bond Activation of Cyclopropanes by Rhodium(II) Porphyrin
  作者：Kin Chan、Shiyu Feng

  DOI：10.1055/s-0036-1589129

  日期：2018.4

  Regioselective carbon–carbon bond activation of cyclopropanes by Rh II (tmp) (tmp = 5,10,15,20-tetramesitylporphyrinato dianion) was achieved at room temperature under neutral conditions to yield corresponding rhodium–porphyrin alkyls. This reaction can tolerate water, and functional groups are compatible.

  在室温和中性条件下，Rh II (tmp) (tmp = 5,10,15,20-四甲基卟啉二价阴离子) 对环丙烷的区域选择性碳-碳键活化得到相应的铑-卟啉烷基。该反应可耐水，且官能团相容。