2-(methyl(phenyl)amino)ethyl benzoate | 20322-87-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(methyl(phenyl)amino)ethyl benzoate
• 英文别名: 1-benzoyloxy-2-(N-methyl-anilino)-ethane；2-[N-Methyl-anilino=>-1-benzyloxy-aethan；1-Benzoyloxy-2-(N-methyl-anilino)-aethan；Benzoesaeure-(β-methylanilino-aethyl)-ester；Methyl-(β-benzoyloxy-aethyl)-anilin；(β-Methylanilino-aethyl)-benzoat；2-(N-methylanilino)ethyl benzoate
• CAS: 20322-87-6
• 化学式: C₁₆H₁₇NO₂
• 分子量: 255.316
• InChiKey: UFZFEZTXVXULMZ-UHFFFAOYSA-N

物化性质

• 熔点：
  48-49 °C
• 沸点：
  184-186 °C(Press: 33 Torr)
• 密度：
  1.128±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(methyl(phenyl)amino)ethyl benzoate 在 盐酸 、 sodium nitrite 作用下， 生成 1-benzoyloxy-2-(N-methyl-4-nitroso-anilino)-ethane
  参考文献：
  名称：

  v. Braun; Kirschbaum, Chemische Berichte, 1919, vol. 52, p. 2015

  摘要：

  DOI：
• 作为产物：
  描述：

  N-(2-溴乙基)-N-甲基苯胺 在 盐酸 作用下， 生成 2-(methyl(phenyl)amino)ethyl benzoate
  参考文献：
  名称：

  v.Braun; Kirschbaum, Chemische Berichte, 1919, vol. 52, p. 1719

  摘要：

  DOI：

文献信息

• Gault, Bulletin de la Societe Chimique de France, 1908, vol. <4>3, p. 374
  作者：Gault

  DOI：——

  日期：——
• Using functionalized nonlinear optical chromophores to prepare NLO-active polycarbonate films
  作者：M. González-Lainez、M.T. Jiménez-Ruiz、N. Martínez de Baroja、J. Garín、J. Orduna、B. Villacampa、M.J. Blesa

  DOI：10.1016/j.dyepig.2015.02.026

  日期：2015.8

  Novel functionalized second order nonlinear optical (NLO) chromophores have been prepared with functionalized aniline as electron donor, thiophene or isophorone as a pi-spacer and 1,3-diethyl-2-thiobarbituric acid as electron acceptor. The films prepared from dyes with alkylsilyl bulky groups gave better performance than the corresponding non functionalized chromophores due to the reduction of the intermolecular electrostatic interactions. The incorporation of chromophores 4 and 10 in a polycarbonate matrix allowed the preparation of good optical-quality films. Nonlinear coefficients d(33) and d(31) as high as 17 and 5.6 pm V-1, respectively, were obtained. Moreover, the temporal stability of these hostguest films was confirmed up to eight months (>80%). (C) 2015 Elsevier Ltd. All rights reserved.
• Schorigin; Below, Chemische Berichte, 1935, vol. 68, p. 833,837
  作者：Schorigin、Below

  DOI：——

  日期：——
• PATTERNING PROCESS, RESIST COMPOSITION, POLYMER, AND POLYMERIZABLE ESTER COMPOUND
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20130157194A1

  公开（公告）日：2013-06-20

  A negative pattern is formed by applying a resist composition onto a substrate, prebaking, exposing to high-energy radiation, baking (PEB), and developing the exposed resist film in an organic solvent developer to dissolve the unexposed region of resist film. The resist composition comprising a polymer adapted to form a lactone ring under the action of an acid so that the polymer may reduce its solubility in an organic solvent developer, an acid generator, and an organic solvent displays a high dissolution contrast between the unexposed region of promoted dissolution and the exposed region of inhibited dissolution.
• US4051084A
  申请人：——

  公开号：US4051084A

  公开（公告）日：1977-09-27