N-(2-(phenylseleno)ethyl)-N-(imidazol-2-ylmethylene)amine | 1422347-31-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(2-(phenylseleno)ethyl)-N-(imidazol-2-ylmethylene)amine
• 英文别名: 1-(1H-imidazol-2-yl)-N-(2-phenylselanylethyl)methanimine
• CAS: 1422347-31-6
• 化学式: C₁₂H₁₃N₃Se
• 分子量: 278.215
• InChiKey: MBUKBJGZPPHUTJ-UHFFFAOYSA-N

物化性质

• 沸点：
  437.8±51.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.28
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  41
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  cobalt(II) chloride hexahydrate 、 N-(2-(phenylseleno)ethyl)-N-(imidazol-2-ylmethylene)amine 以 乙醇 、 二氯甲烷 为溶剂， 以40%的产率得到[N-(2-(phenylseleno)ethyl)-N-(imidazol-2-ylmethylene)amine]cobalt(II) dichloride
  参考文献：
  名称：

  Novel copper(II) and cobalt(II) complexes with selenium substituted imidazolyl imines. The molecular and crystal structure of [N-(2-(phenylseleno)ethyl)-N-(imidazol-2-ylmethylene)amine]copper(II) dichloride

  摘要：

  A series of copper(II) and cobalt(II) complexes with novel selenium containing Schiff base ligands obtained from 2- or 3-aminoalkyl phenyl selenides and imidazole carbaldehydes have been synthesized by the interaction of corresponding organic ligands with MCl2 center dot 6H(2)O (M = Cu, Co). The crystal structure of a copper(II) complex with N-(2-(phenylseleno)ethyl)-N-(imidazolyl-2-ylmethylene)amine has been solved by a single-crystal X-ray diffraction method. The copper(II) ions are coordinated by the imine and imidazole nitrogen atoms of organic ligands and two chloride anions in a distorted square planar geometry. The electrochemical investigations of the synthesized ligands and complexes have been made by cyclic voltammetry method. It is established that the first stage of complexes reduction takes place to metal and the reduced forms of complexes are stable in the solution. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.11.039
• 作为产物：
  描述：

  2-(phenylselanyl)ethanamine hydrochloride 在 potassium hydroxide 作用下， 以 乙醇 为溶剂， 反应 7.0h， 生成 N-(2-(phenylseleno)ethyl)-N-(imidazol-2-ylmethylene)amine
  参考文献：
  名称：

  Novel copper(II) and cobalt(II) complexes with selenium substituted imidazolyl imines. The molecular and crystal structure of [N-(2-(phenylseleno)ethyl)-N-(imidazol-2-ylmethylene)amine]copper(II) dichloride

  摘要：

  A series of copper(II) and cobalt(II) complexes with novel selenium containing Schiff base ligands obtained from 2- or 3-aminoalkyl phenyl selenides and imidazole carbaldehydes have been synthesized by the interaction of corresponding organic ligands with MCl2 center dot 6H(2)O (M = Cu, Co). The crystal structure of a copper(II) complex with N-(2-(phenylseleno)ethyl)-N-(imidazolyl-2-ylmethylene)amine has been solved by a single-crystal X-ray diffraction method. The copper(II) ions are coordinated by the imine and imidazole nitrogen atoms of organic ligands and two chloride anions in a distorted square planar geometry. The electrochemical investigations of the synthesized ligands and complexes have been made by cyclic voltammetry method. It is established that the first stage of complexes reduction takes place to metal and the reduced forms of complexes are stable in the solution. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.11.039

文献信息

• 一种含硒咪唑配合物纳米微球及其制备方法和应用
  申请人：杭州师范大学

  公开号：CN113980035A

  公开（公告）日：2022-01-28

  本发明公开一种含硒咪唑配合物纳米微球及其制备方法和应用。含硒咪唑配合物纳米微球，表面带正电荷；主要包括由锌离子和含硒咪唑席夫碱中N原子配位形成的化合物；通过在含硒小分子上引入pH敏感的C＝N键，pH变化能够使配合物纳米微球断键解离，使硒酶模拟物暴露发挥催化作用。配合物纳米微球可作为其它分子的载体，在形成配合物纳米微球的过程中，将被载分子与锌离子配成混合醇或者水溶液加入到一定浓度的含硒小分子溶液中，再搅拌一段时间即可获得装载其它分子的配合物纳米微球溶液，离心洗涤干燥后即可得到装载其它分子的配合物纳米微球粉末。