3-methyl-phenoxathiine-10,10-dioxide | 186133-02-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 英文名称: 3-methyl-phenoxathiine-10,10-dioxide
• 英文别名: 3-Methyl-phenoxathiin-10,10-dioxid；3-Methyl-phenoxathiine 10,10-dioxide；3-methylphenoxathiine 10,10-dioxide
• CAS: 186133-02-8
• 化学式: C₁₃H₁₀O₃S
• 分子量: 246.287
• InChiKey: CBLCADUNWWRLLJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-methyl-phenoxathiine-10,10-dioxide 在 N-溴代丁二酰亚胺(NBS) 、 偶氮二异丁腈 作用下， 以 四氯化碳 为溶剂， 反应 2.0h， 生成 3-bromomethylphenoxathiin-10,10-dioxide
  参考文献：
  名称：

  吩沙星乙酰化和甲酰化中的取向作用

  摘要：

  DOI：

  10.1007/bf01164717
• 作为产物：
  描述：

  3-methylphenoxathiine 在 双氧水 、 溶剂黄146 作用下， 生成 3-methyl-phenoxathiine-10,10-dioxide
  参考文献：
  名称：

  Phenoxthin. II. Extension of the Ferrario Reaction

  摘要：

  DOI：

  10.1021/ja01291a030

文献信息

• CONJUGATED COMPOUND HAVING PHENOXATHIINL, METHOD FOR PREPARING THE SAME AND OLED DEVICE
  申请人：Shenzhen China Star Optoelectronics Technology Co. Ltd.

  公开号：US20160322584A1

  公开（公告）日：2016-11-03

  The disclosure provides a conjugated compound having phenoxathiinl, method for preparing the same and OLED. The conjugated compound has one of the following formulas: Different kinds of electron-rich conjugated aromatic units are reacted with intermediate having phenoxathiinl by Suzuki coupling, Buchwald-Hartwig coupling, or Cu-catalyzed amination of halogenated aromatic hydrocarbons for forming the conjugated compound having phenoxathiin. The prepared novel compound is fluorescent, so that it can be used as the material of light emitting layer of OLED devices.
• ORGANIC ELECTROLUMINESCENT MATERIAL AND ORGANIC OPTOELECTRONIC DEVICE
  申请人：Shanghai Tianma AM-OLED Co., Ltd.

  公开号：US20170256717A1

  公开（公告）日：2017-09-07

  A compound and an organic optoelectronic device are provided. The compound has the following chemical formula (I): In the chemical formula (I), R 1 to R 10 are independently selected from hydrogen, deuterium, C 1 to C 30 alkyl, C 1 to C 30 heteroatomi-substituted alkyl, C 6 to C 30 aryl, and C 2 to C 30 heteroaryl; X 1 is selected from O, S, substituted or unsubstituted imino, substituted methylene, and substituted or unsubstituted silylene. A substituent is selected from hydrogen, deuterium, C 1 to C 30 alkyl, C 1 to C 30 heteroatom-substituted alkyl, C 6 to C 30 aryl, and C 2 to C 30 heteroaryl. A 1 and A 2 are chemical groups independently represented by the following chemical formula (II),
• US9634260B2
  申请人：——

  公开号：US9634260B2

  公开（公告）日：2017-04-25
• Phenoxthin. II. Extension of the Ferrario Reaction
  作者：C. M. Suter、Frank O. Green

  DOI：10.1021/ja01291a030

  日期：1937.12
• Orientation effects in phenoxathiin acetylation and formylation
  作者：O. Maior、D. Stoicescu、D. Gavriliu

  DOI：10.1007/bf01164717

  日期：1996.9