1-(butylthio)-3-(methylthio)propane | 130440-80-1

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 1-(butylthio)-3-(methylthio)propane
• 英文别名: 1-(3-Methylsulfanylpropylsulfanyl)butane
• CAS: 130440-80-1
• 化学式: C₈H₁₈S₂
• 分子量: 178.363
• InChiKey: VGHSQXHZOROOCU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  10
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  [RuCl2(benzene)]2 、 1-(butylthio)-3-(methylthio)propane 以 甲醇 为溶剂， 反应 3.0h， 生成 [(benzene)RuCl{1-(butylthio)-3-(methylthio)propane}]Cl
  参考文献：
  名称：

  Organometallic Ionic Liquids from Cationic Arene–Ruthenium Complexes

  摘要：

  Ionic liquids comprised of cationic arene-ruthenium chelate complexes and the bis-(trifluoromethanesulfonyl)amide anion (=Tf2N), [(arene)-RuCl(L)](Tf2N), where L = MeS(CH2)(n)SR (R = Me, Bu; n = 1-3), Me2N(CH2)(2)NMe2 and arene = p-cymene, C6H6, have been prepared, and their thermal properties, structures, and reactivities have been investigated. These liquids undergo direct ligand exchange reactions in line with their thermal stabilities. Thermogravimetric analysis revealed that the thermal stabilities of the complexes are higher as the bridging group of the chelate ligand becomes longer. The complexes with MeSCH2SMe transform thermally into dinuclear complexes. The coordination structures were determined crystallographically.

  DOI：

  10.1021/om300847s

文献信息

• NAPHTHALOCYANINE COMPOUND AND METHOD FOR PRODUCING THE SAME
  申请人：Kimura Keizo

  公开号：US20090270610A1

  公开（公告）日：2009-10-29

  A naphthalocyanine compound of formula (I): wherein R 111 , R 121 , R 131 and R 141 represent a group of formula (II); R 112 , R 122 , R 132 and R 142 represent a substituent; M 1 represents two hydrogen atoms, two monovalent metal atoms, etc.; n112, n122, n132 and n142 are 0 to 4; R 211 -R 218 represent H or a substituent; X 211 and X 212 represent —O—, —S— or —N(R 220 )—; R 219 and R 220 represent H, an aliphatic group, etc.; n211 is 2 or more; and n212 is 1 or more.
• US7838670B2
  申请人：——

  公开号：US7838670B2

  公开（公告）日：2010-11-23