4-biphenyloxypentyldimethylchlorosilane | 761401-74-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-biphenyloxypentyldimethylchlorosilane
• 英文别名: chloro-dimethyl-[5-(4-phenylphenoxy)pentyl]silane
• CAS: 761401-74-5
• 化学式: C₁₉H₂₅ClOSi
• 分子量: 332.945
• InChiKey: YXPWYEIONLFGIM-UHFFFAOYSA-N

物化性质

• 沸点：
  436.2±38.0 °C(Predicted)
• 密度：
  1.024±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.35
• 重原子数：
  22.0
• 可旋转键数：
  8.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  9.23
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  4-biphenyloxypentyldimethylchlorosilane 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 反应 6.0h， 以70%的产率得到4-biphenyloxypentyldimethylsilane
  参考文献：
  名称：

  Synthesis of novel tri-podal mesogenic alkenes and side-chain polysiloxanes

  摘要：

  Low molecular weight tri-podal biphenyl- and benzoate-type mesogens [C6H5C6H4O(CH2)(5)SiMe2CH2CH2SiMe2](3)CH (4), [C11H23O(C6H4)(2)O(CH2)(5)SiMe2](3)CH (5) and [MeOC6H4OC(O)C6H4O(CH2)(5)SiMe2](3)CH (6) (C6H4 = 1,4-phenylene) were obtained, from branched silyl substituted methane precursors [CH2=CH(Me)(2)Si33CH (1) and (HMe2Si)(3)CH (2). The biphenyl-containing ones (4) and (5) were converted into terminal alkenes, which were subsequently hydrosilylated with poly(methylsiloxanes). The polymer derived from (5) exhibited mesomorphic properties. Such systems have the potential to significantly increase the density of liquid crystal rod-like structures in side chains of linear polymers (or dendritic liquid crystal polymers). (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.05.019
• 作为产物：
  描述：

  二甲基一氯硅烷 、 1-戊-4-烯氧基-4-苯基苯 在 chloroplatinic acid 1,1,3,3-tetramethyl-1,3-divinyldisiloxane complex 作用下， 以 xylene 为溶剂， 反应 24.0h， 以100%的产率得到4-biphenyloxypentyldimethylchlorosilane
  参考文献：
  名称：

  Synthesis of novel tri-podal mesogenic alkenes and side-chain polysiloxanes

  摘要：

  Low molecular weight tri-podal biphenyl- and benzoate-type mesogens [C6H5C6H4O(CH2)(5)SiMe2CH2CH2SiMe2](3)CH (4), [C11H23O(C6H4)(2)O(CH2)(5)SiMe2](3)CH (5) and [MeOC6H4OC(O)C6H4O(CH2)(5)SiMe2](3)CH (6) (C6H4 = 1,4-phenylene) were obtained, from branched silyl substituted methane precursors [CH2=CH(Me)(2)Si33CH (1) and (HMe2Si)(3)CH (2). The biphenyl-containing ones (4) and (5) were converted into terminal alkenes, which were subsequently hydrosilylated with poly(methylsiloxanes). The polymer derived from (5) exhibited mesomorphic properties. Such systems have the potential to significantly increase the density of liquid crystal rod-like structures in side chains of linear polymers (or dendritic liquid crystal polymers). (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.05.019