[Cd(ethylenediamine)3][Cu(isomaleonitriledithiolate)2] | 528817-75-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [Cd(ethylenediamine)3][Cu(isomaleonitriledithiolate)2]
• CAS: 528817-75-6
• 化学式: C₆H₂₄CdN₆*C₈CuN₄S₄
• 分子量: 636.632
• InChiKey: PVYLGBRGCJITJK-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(ll) sulfate pentahydrate 、 cadmium(II) nitrate tetrhydrate 、 1,1-dicyanoethylene-2,2-dithiolate potassium salt 、 乙二胺 以 乙醇 、 水 为溶剂， 以86%的产率得到[Cd(ethylenediamine)3][Cu(isomaleonitriledithiolate)2]
  参考文献：
  名称：

  Preparation, characterization and electrical conductances of heterometallic coordination polymers and complex bimetallic salts derived from isomaleonitriledithiolate

  摘要：

  The complex salts [M(N-N)(3)][Cu(i-mnt)(2)] [M = Fe(II), Co(II), Ni(II) or Cd(II); N-N = 1,10-phenanthroline (phen) or ethylenediamine (en); i-mnt(2-) = isomaleonitriledithiolate] and heterometallic coordination polymers M'Cu(i-mnt)(2) [M' = 2Ag(I), Cd(II), Hg(II) or Pb(II)] have been synthesized by stoichiometric reactions between K-2[Cu(i-mnt)(2)] and [M(N-N)(3)]X-2 or MX2 [X = Cl-, NO3- or 1/2SO(4)(2-)]. These have been characterized by elemental analyses, solution conductivity and magnetic susceptibility measurements, relevant spectroscopies (IR, UV-Visible and EPR) and solid phase conductivity techniques. Complete quenching of paramagnetism shows strong antiferromagnetically coupled Cu(II) ions in the bridged heterometallic complexes M'Cu(i-mnt)2 producing a polymeric array. The coordination polymers M'Cu(i-mnt)(2) exhibit a,, = 10(-9)-10(-6) S cm(-1) and show semiconductivity in the 313-393 K range while complex salts [M(N-N)(3)][Cu(i-mnt)(2)] are insulators at room temperature and at higher temperature as well. Iodine-doped products of complex bimetallic salts and coordination polymers are conducting at room temperature and exhibit semiconducting behaviour over above temperature range. Conductivities of the coordination polymers are significantly higher compared to the bimetallic salts. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(02)00798-0