praseodymium(III)(3-aminobenzoate)(3-NH-C6H4-COO(2-)) | 1131403-40-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: praseodymium(III)(3-aminobenzoate)(3-NH-C6H4-COO(2-))
• CAS: 1131403-40-1
• 化学式: C₇H₅NO₂*C₇H₆NO₂*Pr
• 分子量: 412.16
• InChiKey: CCLYBGKEMGAFLU-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  间氨基苯甲酸 、 praseodymium oxide 在 TlNO₃ 作用下， 以 乙醇 为溶剂， 生成 praseodymium(III)(3-aminobenzoate)(3-NH-C6H4-COO(2-))
  参考文献：
  名称：

  Two 3-aminobenzoates of praseodymium, Pr(OOC-Ph-NH2)3(H2O) and Pr(OOC-Ph-NH2)(OOC-Ph-NH)

  摘要：

  In the monohydrate Pr(OOC-Ph-NH2)(3)(H2O) (1), Pr3+ is nine-coordinate with only oxygen atoms coordinating. Two carboxylate groups are bidentate-bridging, four are tridentate-bridging and there is one coordinating water molecule, hence the coordination number is nine. The chains run along [010]. In the anhydrous Pr(OOC-Ph-NH2)(OOC-Ph-NH) (2), the central Pr3+ ion is surrounded by six oxygen atoms and two nitrogen atoms in a distorted square antiprism. These polyhedra are connected to each other via two opposite O-O edges to form chains running parallel [001]. The chains, in which all carboxylate groups are tridentate-bridging, are arranged in a centered rectangular fashion and are further connected via OOC-Ph-NH bridging. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2007.04.230