[Ni(N-2-CH3C6H4-sulfonyldithiocarbimato)(1,2-bis(diphenylphosphine)ethane)] | 1017597-65-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ni(N-2-CH3C6H4-sulfonyldithiocarbimato)(1,2-bis(diphenylphosphine)ethane)]
• CAS: 1017597-65-7
• 化学式: C₃₄H₃₁NNiO₂P₂S₃
• 分子量: 702.461
• InChiKey: GNKUGNKNRRWBFX-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  1,2-双(二苯基膦)乙烷 、 nickel(II) chloride hexahydrate 、 potassium 2-methylphenyldithiocarbimate dihydrate 以 乙醇 、 水 为溶剂， 以70%的产率得到[Ni(N-2-CH3C6H4-sulfonyldithiocarbimato)(1,2-bis(diphenylphosphine)ethane)]
  参考文献：
  名称：

  Syntheses, crystal structure and spectroscopic characterization of novel 1,2-bis(diphenylphosphine)ethane(N-R-sulfonyldithiocarbimato)nickel(II) complexes

  摘要：

  Three new complexes of the general formula: [Ni(RSO2N=CS2)(dppe)], where R = CH3(1), CH3CH2 (2), 2-CH3C6H4 (3) and dppe = 1,2-bis(diphenylphosphine)ethane, were obtained in crystalline form by the one-pot reaction of the appropriate potassium N-R-sulfonyldithiocarbimate: RSO2N=CS2K2 center dot 2H(2)O and 1,2-bis(diphenylphosphine)ethane with nickel(II) chloride hexahydrate in ethanol/water mixture. The complex 1 forms monoclinic crystals (P2(1)/c) with two molecules in the asymmetric unit (Z = 8), while the crystals of the complexes 2 and 3 are orthorhombic, Pbca (Z = 8) and P2(1)2(1)2(1) (Z = 4) respectively, with one molecule in the asymmetric unit. All complexes present a distorted square-planar environment around the Ni atom. The elemental analyses and the IR, H-1 NMR, C-13 NMR and P-31 NMR spectra are consistent with the formation of the nickel(II) complexes with mixed ligands. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.11.001