2-[N-ethyl-N-[4-[2-[2-(3,4-dibutyl)thienyl]ethenyl]phenyl]amino]ethyl ethanoate | 1022089-86-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-[N-ethyl-N-[4-[2-[2-(3,4-dibutyl)thienyl]ethenyl]phenyl]amino]ethyl ethanoate
• CAS: 1022089-86-6
• 化学式: C₂₆H₃₇NO₂S
• 分子量: 427.651
• InChiKey: RFNWVJBJOYSYKL-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  2-[N-ethyl-N-[4-[2-[2-(3,4-dibutyl)thienyl]ethenyl]phenyl]amino]ethyl ethanoate 、 N,N-二甲基甲酰胺 在 三氯氧磷 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 18.0h， 生成 2-[N-ethyl-N-[4-[2-[2-(3,4-dibutyl)thiene-5-carbaldehyde]ethenyl]phenyl]amino]ethyl ethanoate 、 2-[N-ethyl-N-[4-[2-[2-(3,4-dibutyl)thiene-5-carbaldehyde]ethenyl]phenyl]amino]ethyl ethanoate
  参考文献：
  名称：

  Synthesis and nonlinear optical properties of linear and Λ-shaped pyranone-based chromophores

  摘要：

  New, pyranone-based chromophores were synthesized and their (nonlinear) optical properties were measured. The chromophores were prepared by first condensing an electron withdrawing group with pyranone, followed by reaction with an aldehyde-functionalized pi-conjugated bridged donor molecule. This approach enables one to easily incorporate the pyranone moiety and to prepare both linear and A-shaped chromophores. The (nonlinear) optical properties were measured using femtosecond hyper-Rayleigh scattering. These measurements demonstrated the advantages of this approach. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.02.009