[N,N'-ethylenebis(thiosalicylideneiminato)nickel(II)] | 19621-41-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [N,N'-ethylenebis(thiosalicylideneiminato)nickel(II)]
• 英文别名: (N,N'-ethylenebis(thiosalicylidenaminato))nickel(II)；N,N'-ethylene-bis(thiosalicylideneiminato)nickel(II)；[Ni(N,N'-ethylenebis(thiosalicylidene)imine)]；[Ni(bis(thiosalicylidene)imine(2-))]；[Ni(tsalen)]；Ni(N,N'-ethylenebis(o-mercaptobenzylidenamine))
• CAS: 19621-41-1
• 化学式: C₁₆H₁₄N₂NiS₂
• 分子量: 357.123
• InChiKey: UIVIMQXBRAWUFI-OYJDLGDISA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.33
• 重原子数：
  21.0
• 可旋转键数：
  0.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  24.72
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  iron (III) chloride hexahydrate 、 [N,N'-ethylenebis(thiosalicylideneiminato)nickel(II)] 以 乙醇 、 二氯甲烷 为溶剂， 以42%的产率得到[BBITE(2+)][Ni(tsalen)]4[FeCl4(1-)]
  参考文献：
  名称：

  通过 Ni(tsalen) 与 FeCl3 的氧化解络合形成乙烯桥连的双（苯并异噻唑）二阳离子

  摘要：

  摘要 用 FeCl3 处理 Ni(tsalen)，其中 H2tsalen = 双（硫代水杨烯）亚胺导致分离出具有 [BBITE2+][Ni(tsalen)]4[FeCl4-]2 (I) 组成的结晶化合物，其中 BBITE =1,2-双(1,2-苯并异噻唑-2-基)乙烷。BBITE2+ 阳离子的产生代表了 tsalen2- 配体的 4 电子氧化，尽管 FeCl3 不是一种足够强的氧化剂来促进 Ni(tsalen) 复合物的任何外球氧化。I 的晶体结构显示了一系列由 [Ni(tsalen)] 和 BBITE2+ 分子之间的非共价相互作用维持的通道。

  DOI：

  10.1016/s1387-7003(02)00693-7
• 作为产物：
  描述：

  tris(ethane-1,2-diamine)nickel(II) chloride 、 2,2'-dithiodibenzaldehyde 以 二氯甲烷 为溶剂， 以77%的产率得到[N,N'-ethylenebis(thiosalicylideneiminato)nickel(II)]
  参考文献：
  名称：

  Goswami, Niranjan; Eichhorn, David M., Inorganic Chemistry, 1999, vol. 38, # 19, p. 4329 - 4333

  摘要：

  DOI：

文献信息

• Oxidative addition of disulfide/diselenide to group 10 metal(0) and in situ functionalization to form neutral thiasalen/selenasalen group 10 metal(<scp>ii</scp>) complexes
  作者：Pradip Kr. Dutta、Ashish K. Asatkar、Sanjio S. Zade、Snigdha Panda

  DOI：10.1039/c3dt52132j

  日期：——

  thiasalen/selenasalen Ni(II), Pd(II) and Pt(II) complexes, 14–19, by the oxidative addition of S–S/Se–Se bond of bis(o-formylphenyl)disulfide/-diselenide to Ni(0), Pd(0) and Pt(0) followed by in situ Schiff base formation with ethylenediamine is reported. S–S or Se–Se bonds were cleaved and coordinated to the metal center as thiolate (ArS−) or selenolate (ArSe−) while the formal oxidation state of metal centers

  三组分，通过氧化加成双（邻-甲酰基苯基）的S-S / Se-Se键，一锅合成噻唑仑/硒代硒仑Ni（II），Pd（II）和Pt（II）配合物（14-19）。据报道，将二硫化物/二硒化为Ni（0），Pd（0）和Pt（0），然后与乙二胺原位形成席夫碱。S-S或Se-Se系粘合体裂解和配位到金属中心如硫醇（ARS - ）或selenolate（驴-），而金属中心的形式氧化态从'0'变为'+2'。二硫化物/二硒化物在室温下与零价金属反应，仅得到单金属配合物。所有的配合物（Pd-硫醇盐配合物15除外）均通过单晶X射线晶体学研究，并揭示了金属中心周围的方形平面几何形状。
• Syntheses and Structures of NiS₂N₂Compounds. [<i>N,N</i>′-Bis(<i>o</i>-mercaptobenzyliden)ethylenediaminato]nickel(II), Ni(tsalen), and [<i>N,N</i>′-Bis(<i>o</i>-mercaptobenzyl)ethylenediaminato]nickel(II), Ni(ebmba)
  作者：Takeshi Yamamura、Makoto Tadokoro、Koji Tanaka、Reiko Kuroda

  DOI：10.1246/bcsj.66.1984

  日期：1993.7

  The syntheses, structures, absorption spectra, and redox potentials of Ni(tsalen), H2tsalen = N,N′-bis(o-mercaptobenzyliden)ethylenediamine, and Ni(ebmba), H2ebmba = N,N′-bis(o-mercaptobenzyl)ethylenediamine, are described. Ni(tsalen) was prepared directly from N,N′-bis(o-t-buthylthiobenzyliden)ethylenediamine, from which H2ebmba and, subsequently, Ni(ebmba) were also prepared. The crystal data for these two complexes are as follows: 1) Ni(tsalen); space group Pna21 with the unit-cell dimensions a = 8.929(1), b = 22.603(2), c = 7.484(1) Å, Z = 4, 2) Ni(ebmba); space group P21/c, a = 13.324(5), b = 7.9263(8), c = 15.262(3) Å, β = 101.23(2)°. Ni(tsalen) and Ni(ebmba) adopt squareplanar geometries with average Ni–S distances of 2.157 and 2.165 Å, respectively. The Ni–N distances of these complexes are 1.85(5) and 1.945 Å, respectively. These values, as well as the redox potentials and absorption maxima, ware compared with those of another type of NiS2N2 compound, [Ni(ebtsa)]2−; H4ebtsa = N,N′-bis(o-mercaptobenzoyl)ethlenediamide.

  介绍了 Ni(tsalen)（H2tsalen = N,N′-双(邻巯基亚苄基)乙二胺）和 Ni(ebmba)（H2ebmba = N,N′-双(邻巯基亚苄基)乙二胺）的合成、结构、吸收光谱和氧化还原电位。Ni(tsalen) 由 N,N′-双(邻叔丁基硫代苄基)乙二胺直接制备，H2ebmba 和 Ni(ebmba) 也是由它制备的。这两种配合物的晶体数据如下：1) Ni(tsalen)；空间群 Pna21，单位晶胞尺寸 a = 8.929(1)，b = 22.603(2)，c = 7.484(1)埃，Z = 4，2) Ni(ebmba)；空间群 P21/c，a = 13.324(5)，b = 7.9263(8)，c = 15.262(3)埃，β = 101.23(2)°。Ni(tsalen) 和 Ni(ebmba) 采用方形几何结构，平均 Ni-S 间距分别为 2.157 Å 和 2.165 Å。这些复合物的 Ni-N 间距分别为 1.85(5) Å 和 1.945 Å。这些值以及氧化还原电位和吸收最大值与另一类 NiS2N2 复合物 [Ni(ebtsa)]2- 的值进行了比较；H4ebtsa = N,N′-双（邻巯基苯甲酰基）乙二胺。
• Incorporation of thiolate donation using 2,2′-dithiodibenzaldehyde: synthesis of Ni, Fe, and Cu complexes. Crystal structures of [M(tsalen)] (tsalen=N,N′-ethylenebis(thiosalicylidene)imine); M=Cu, Ni) showing a tetrahedral distortion of Cu(tsalen)
  作者：Niranjan Goswami、David M Eichhorn

  DOI：10.1016/s0020-1693(00)00047-5

  日期：2000.5

  Ethylenediamine complexes of Ni(II), Fe(III), and Cu(II) are combined with 2,2'-dithiodibenzaldehyde (DTDB) to form complexes with mixed N/S coordination spheres, demonstrating the generality of this synthetic methodology for metals other than Ni(II). Fe(en)(3)(3+) reacts with DTDB to give Fe(Haetsaln)(2)(+) (Haetsaln = N-(2-aminoethyl)thiosalicylideneimine), stemming from the addition of a thiobenzaldehyde moiety from DTDB to one of the ethylenediamine N atoms. Ni(en)(3)(2+) and Cu(en)(2)(2+) react with DTDB to give Ni(tsalen) and Cu(tsalen) (tsalen = N,N'-ethylenebis(thiosalicylideneimine), stemming from the addition of a thiobenzaldehyde moiety to both ethylenediamine N atoms. A new crystal structure for Ni(tsalen) is reported, as well as the first crystal structure of Cu(tsalen), which shows a significant deviation from planarity in the N2S2 coordination sphere. (C) 2000 Elsevier Science S.A. All rights reserved.
• Yamamura, Takeshi; Tadokoro, Makoto; Kuroda, Reiko, Chemistry Letters, 1989, p. 1245 - 1246
  作者：Yamamura, Takeshi、Tadokoro, Makoto、Kuroda, Reiko

  DOI：——

  日期：——