poly[aquacadmium-bis(μ-nicotinato-κN:κO,κO')] | 910874-65-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: poly[aquacadmium-bis(μ-nicotinato-κN:κO,κO')]
• 英文别名: aquacadmium bisnicotinate
• CAS: 910874-65-6；161962-12-5
• 化学式: C₁₂H₁₀CdN₂O₅
• 分子量: 374.632
• InChiKey: RQAMUKMBQALAIB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  烟酸 、 无水碳酸镉 以 水 为溶剂， 生成 poly[aquacadmium-bis(μ-nicotinato-κN:κO,κO')]
  参考文献：
  名称：

  The Polymeric Structure of Aquacadmium Bisnicotinate

  摘要：

  The title compound, poly[aquacadmium-bis(mu-nicotinato-kN:kO,kO')], [Cd(C6H4NO2)2(H2O)], consists of a polymeric network in which each nicotinate acts as a bidentate chelating ligand towards one Cd atom through its carboxylate group while simultaneously binding to a second Cd atom through its pyridine N atom. Cd has approximate pentagonal bipyramidal coordination geometry. Water acts as a ligand; it is also involved in hydrogen bonding to nearby carboxylate O atoms, contributing further to the polymeric network interactions.

  DOI：

  10.1107/s0108270194007249