Bis-(2-methyl-1-naphthyl)-keton | 72769-75-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bis-(2-methyl-1-naphthyl)-keton
• 英文别名: Bis(2-methyl-1-naphthyl) ketone；bis(2-methylnaphthalen-1-yl)methanone
• CAS: 72769-75-6
• 化学式: C₂₃H₁₈O
• 分子量: 310.395
• InChiKey: CJIHORNZTHVLJR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Bis-(2-methyl-1-naphthyl)-keton 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 生成 Bis-(2-methyl-naphthalen-1-yl)-methanol
  参考文献：
  名称：

  Cervinka,O. et al., Collection of Czechoslovak Chemical Communications, 1979, vol. 44, p. 2946 - 2969

  摘要：

  DOI：
• 作为产物：
  描述：

  1-溴-2-甲基萘 、 2-甲基萘-1-甲酰氯 生成 Bis-(2-methyl-1-naphthyl)-keton
  参考文献：
  名称：

  Cervinka,O. et al., Collection of Czechoslovak Chemical Communications, 1979, vol. 44, p. 2946 - 2969

  摘要：

  DOI：

文献信息

• LILIAN SURROGATE
  申请人：Huchel Ursula

  公开号：US20120004328A1

  公开（公告）日：2012-01-05

  Due to toxicological concerns, it may be desirable to replace the fragrance compound lilial with less problematic compounds without losing the creative power and quality regarding perfumes. The present invention addresses this need by using selected oxazolidines described herein.

  由于毒理学方面的担忧，可能希望用更少问题的化合物替代香料化合物lilial，而不会失去有关香水的创造力和质量。本发明通过使用此处所述的选择性噁唑烷来解决这个需求。
• [EN] MACROCYCLIC TRIENE LACTONES HAVING UNCONJUGATED TRIENE STRUCTURE, ITS PRODUCTION METHOD AND ITS SYNTHETIC INTERMEDIATE<br/>[FR] LACTONES TRIÉNIQUES MACROCYCLIQUES AYANT UNE STRUCTURE TRIÉNIQUE NON CONJUGUÉE, SON PROCÉDÉ DE PRODUCTION ET SON INTERMÉDIAIRE DE SYNTHÈSE
  申请人：TAKASAGO PERFUMERY CO LTD

  公开号：WO2012115285A1

  公开（公告）日：2012-08-30

  The present invention provides a novel macrocyclic compound exhibiting superior odor qualities and having a musk-like aroma, a method for producing the same, and a novel flavor or fragrance composition, and food products or beverages, fragrances or cosmetics, daily necessities or household goods and oral products using the novel macrocyclic compound. The invention relates to a compound represented by the formula (1), wherein each of wavy lines represents at least one of an E-configuration of C=C double bond and an Z-configuration of C=C double bond; m represents an integer of 0 to 10; and n represents an integer of 1 to 11, and n represents an integer of 1 to 11 when m is 0 to 4 or 6 to 10, and n is an integer of 1or 3 to 11 when m is 5.

  本发明提供了一种新型的大环化合物，具有优异的气味特性和麝香般的香气，以及制备该化合物的方法和一种新型的风味或香料组合物，以及使用该新型大环化合物的食品或饮料、香水或化妆品、日用品或家居用品和口腔产品。该发明涉及一种由式（1）表示的化合物，其中波浪线表示C=C双键的E构型和Z构型中的至少一个；m表示0到10的整数；n表示1到11的整数，当m为0到4或6到10时，n表示1到11的整数，当m为5时，n表示1或3到11的整数。
• New nitromethyl ketones, process for preparing them and compositions containing them
  申请人：Merck Patent GmbH

  公开号：US20030171422A1

  公开（公告）日：2003-09-11

  The present invention relates to the compounds of formula: 1 in which R 1 , R 2 , R 3 , E, A, X, Z, p and n are as defined herein. These compounds are aldose reductase inhibitors.

  本发明涉及公式1中的化合物：其中R1，R2，R3，E，A，X，Z，p和n的定义如本文所述。这些化合物是醛糖还原酶抑制剂。
• MACROCYCLIC TRIENE LACTONES HAVING UNCONJUGATED TRIENE STRUCTURE, ITS PRODUCTION METHOD AND ITS SYNTHETIC INTERMEDIATE
  申请人：Inaba Teruhiko

  公开号：US20130324744A1

  公开（公告）日：2013-12-05

  The present invention provides a novel macrocyclic compound exhibiting superior odor qualities and having a musk-like aroma, a method for producing the same, and a novel flavor or fragrance composition, and food products or beverages, fragrances or cosmetics, daily necessities or household goods and oral products using the novel macrocyclic compound. The invention relates to a compound represented by the formula (1), wherein each of wavy lines represents at least one of an E-configuration of C═C double bond and an Z-configuration of C═C double bond; m represents an integer of 0 to 10; and n represents an integer of 1 to 11, and n represents an integer of 1 to 11 when m is 0 to 4 or 6 to 10, and n is an integer of 1 or 3 to 11 when m is 5.

  本发明提供了一种新型大环化合物，具有卓越的气味特性和麝香般的香气，以及其制备方法、新型风味或香料组合物和使用该新型大环化合物的食品或饮料、香料或化妆品、日用品或家居用品和口腔产品。该发明涉及一种由公式（1）表示的化合物，其中波浪线表示C = C双键的E构型和Z构型中的至少一个；m表示0至10的整数；n表示1至11的整数，当m为0至4或6至10时，n表示1至11的整数，当m为5时，n表示1或3至11的整数。
• Perfume composition
  申请人：QUEST INTERNATIONAL NEDERLAND BV

  公开号：EP0545556A2

  公开（公告）日：1993-06-09

  A perfume composition contains at least 50% by weight of materials which fall into five categories defined by structure, and molecular weight. Amounts of material within each category satisfy specified minimum percentages of the whole composition. At least four categories out of five must be present. These five categories are ethers, salicylates, alcohols, acetate/propionate esters and methyl aryl ketones. The compositions enable good levels of deodorant activity to be achieved along with consumer-acceptable fragrance.

  按重量计，香水成分至少含有 50%的材料，这些材料按结构和分子量分为五类。每个类别中的材料数量都要满足整个成分中规定的最低百分比。五个类别中必须至少有四个类别。这五类分别是醚、水杨酸酯、醇、醋酸酯/丙酸酯和甲基芳基酮。 这种组合物不仅具有良好的除臭活性，而且还具有消费者可接受的香味。